Nickel-catalyzed reductive thiolation and selenylation of unactivated alkyl bromides

Chalcogen-containing compounds find broad application in chemical industry. Here, the authors report a nickel-catalyzed reductive chalcogenation of unactivated alkyl bromides with thiosulfonates and selenosulfonates to access a range of unsymmetrical sulfides and selenides under mild conditions.

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Autores principales: Yi Fang, Torben Rogge, Lutz Ackermann, Shun-Yi Wang, Shun-Jun Ji
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/5a6a88e661cd4a629ba139e7e843fa3d
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