Catalytic Synthesis of the Biofuel 5-Ethoxymethylfurfural (EMF) from Biomass Sugars

A new generation of bioplatform molecule 5-ethoxymethylfurfural (EMF) has excellent energy density and combustion performance, which makes it a potential fuel additive. This article reviews the factors that affect the production of EMF from different feedstocks, including platform compounds, monosac...

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Autores principales:	Dayong Yu, Xiaofang Liu, Jingjing Jiang, Yixuan Liu, Jinyu Tan, Hu Li
Formato:	article
Lenguaje:	EN
Publicado:	Hindawi Limited 2021
Materias:	Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/5a6f1c2b0234483aa62c24d0da43482c
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spelling	oai:doaj.org-article:5a6f1c2b0234483aa62c24d0da43482c2021-11-15T01:19:12ZCatalytic Synthesis of the Biofuel 5-Ethoxymethylfurfural (EMF) from Biomass Sugars2090-907110.1155/2021/9015481https://doaj.org/article/5a6f1c2b0234483aa62c24d0da43482c2021-01-01T00:00:00Zhttp://dx.doi.org/10.1155/2021/9015481https://doaj.org/toc/2090-9071A new generation of bioplatform molecule 5-ethoxymethylfurfural (EMF) has excellent energy density and combustion performance, which makes it a potential fuel additive. This article reviews the factors that affect the production of EMF from different feedstocks, including platform compounds, monosaccharides, polysaccharides, and raw lignocellulosic biomass. Focus is placed on discussing the catalytic efficiency with pros and cons of different acid catalysts, including homogeneous catalysts (i.e., liquid acids and metal salts), heterogeneous catalysts (i.e., zeolites, heteropolyacid-based hybrids, and SO3H-based catalysts), ionic liquids, mixed acid catalysts, and deep eutectic solvents (DESs). Except for the commonly used ethanol solvent, this review also summarizes the influence of the cosolvent system (e.g., ethanol/dimethylsulfoxide (DMSO), ethanol/tetrahydrofuran (THF), and ethanol/γ-valerolactone (GVL)) on the EMF yield.Dayong YuXiaofang LiuJingjing JiangYixuan LiuJinyu TanHu LiHindawi LimitedarticleChemistryQD1-999ENJournal of Chemistry, Vol 2021 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Chemistry QD1-999
spellingShingle	Chemistry QD1-999 Dayong Yu Xiaofang Liu Jingjing Jiang Yixuan Liu Jinyu Tan Hu Li Catalytic Synthesis of the Biofuel 5-Ethoxymethylfurfural (EMF) from Biomass Sugars
description	A new generation of bioplatform molecule 5-ethoxymethylfurfural (EMF) has excellent energy density and combustion performance, which makes it a potential fuel additive. This article reviews the factors that affect the production of EMF from different feedstocks, including platform compounds, monosaccharides, polysaccharides, and raw lignocellulosic biomass. Focus is placed on discussing the catalytic efficiency with pros and cons of different acid catalysts, including homogeneous catalysts (i.e., liquid acids and metal salts), heterogeneous catalysts (i.e., zeolites, heteropolyacid-based hybrids, and SO3H-based catalysts), ionic liquids, mixed acid catalysts, and deep eutectic solvents (DESs). Except for the commonly used ethanol solvent, this review also summarizes the influence of the cosolvent system (e.g., ethanol/dimethylsulfoxide (DMSO), ethanol/tetrahydrofuran (THF), and ethanol/γ-valerolactone (GVL)) on the EMF yield.
format	article
author	Dayong Yu Xiaofang Liu Jingjing Jiang Yixuan Liu Jinyu Tan Hu Li
author_facet	Dayong Yu Xiaofang Liu Jingjing Jiang Yixuan Liu Jinyu Tan Hu Li
author_sort	Dayong Yu
title	Catalytic Synthesis of the Biofuel 5-Ethoxymethylfurfural (EMF) from Biomass Sugars
title_short	Catalytic Synthesis of the Biofuel 5-Ethoxymethylfurfural (EMF) from Biomass Sugars
title_full	Catalytic Synthesis of the Biofuel 5-Ethoxymethylfurfural (EMF) from Biomass Sugars
title_fullStr	Catalytic Synthesis of the Biofuel 5-Ethoxymethylfurfural (EMF) from Biomass Sugars
title_full_unstemmed	Catalytic Synthesis of the Biofuel 5-Ethoxymethylfurfural (EMF) from Biomass Sugars
title_sort	catalytic synthesis of the biofuel 5-ethoxymethylfurfural (emf) from biomass sugars
publisher	Hindawi Limited
publishDate	2021
url	https://doaj.org/article/5a6f1c2b0234483aa62c24d0da43482c
work_keys_str_mv	AT dayongyu catalyticsynthesisofthebiofuel5ethoxymethylfurfuralemffrombiomasssugars AT xiaofangliu catalyticsynthesisofthebiofuel5ethoxymethylfurfuralemffrombiomasssugars AT jingjingjiang catalyticsynthesisofthebiofuel5ethoxymethylfurfuralemffrombiomasssugars AT yixuanliu catalyticsynthesisofthebiofuel5ethoxymethylfurfuralemffrombiomasssugars AT jinyutan catalyticsynthesisofthebiofuel5ethoxymethylfurfuralemffrombiomasssugars AT huli catalyticsynthesisofthebiofuel5ethoxymethylfurfuralemffrombiomasssugars
_version_	1718428984911331328

Catalytic Synthesis of the Biofuel 5-Ethoxymethylfurfural (EMF) from Biomass Sugars

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