Controlling reaction pathways of selective C–O bond cleavage of glycerol

The hydrodeoxygenation (HDO) reaction is an important pathway to upgrade glycerol, but a fundamental explanation for the selectivity toward breaking different number and type of the CO bonds is still lacking. Here, the authors explore the possibility of tuning the HDO selectivity by manipulating the...

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Autores principales:	Weiming Wan, Salai C. Ammal, Zhexi Lin, Kyung-Eun You, Andreas Heyden, Jingguang G. Chen
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/5a94542d8b74428aa63a5eea6fb9b455
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spelling	oai:doaj.org-article:5a94542d8b74428aa63a5eea6fb9b4552021-12-02T15:33:58ZControlling reaction pathways of selective C–O bond cleavage of glycerol10.1038/s41467-018-07047-72041-1723https://doaj.org/article/5a94542d8b74428aa63a5eea6fb9b4552018-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-07047-7https://doaj.org/toc/2041-1723The hydrodeoxygenation (HDO) reaction is an important pathway to upgrade glycerol, but a fundamental explanation for the selectivity toward breaking different number and type of the CO bonds is still lacking. Here, the authors explore the possibility of tuning the HDO selectivity by manipulating the surface oxophilicity.Weiming WanSalai C. AmmalZhexi LinKyung-Eun YouAndreas HeydenJingguang G. ChenNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-10 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Weiming Wan Salai C. Ammal Zhexi Lin Kyung-Eun You Andreas Heyden Jingguang G. Chen Controlling reaction pathways of selective C–O bond cleavage of glycerol
description	The hydrodeoxygenation (HDO) reaction is an important pathway to upgrade glycerol, but a fundamental explanation for the selectivity toward breaking different number and type of the CO bonds is still lacking. Here, the authors explore the possibility of tuning the HDO selectivity by manipulating the surface oxophilicity.
format	article
author	Weiming Wan Salai C. Ammal Zhexi Lin Kyung-Eun You Andreas Heyden Jingguang G. Chen
author_facet	Weiming Wan Salai C. Ammal Zhexi Lin Kyung-Eun You Andreas Heyden Jingguang G. Chen
author_sort	Weiming Wan
title	Controlling reaction pathways of selective C–O bond cleavage of glycerol
title_short	Controlling reaction pathways of selective C–O bond cleavage of glycerol
title_full	Controlling reaction pathways of selective C–O bond cleavage of glycerol
title_fullStr	Controlling reaction pathways of selective C–O bond cleavage of glycerol
title_full_unstemmed	Controlling reaction pathways of selective C–O bond cleavage of glycerol
title_sort	controlling reaction pathways of selective c–o bond cleavage of glycerol
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/5a94542d8b74428aa63a5eea6fb9b455
work_keys_str_mv	AT weimingwan controllingreactionpathwaysofselectivecobondcleavageofglycerol AT salaicammal controllingreactionpathwaysofselectivecobondcleavageofglycerol AT zhexilin controllingreactionpathwaysofselectivecobondcleavageofglycerol AT kyungeunyou controllingreactionpathwaysofselectivecobondcleavageofglycerol AT andreasheyden controllingreactionpathwaysofselectivecobondcleavageofglycerol AT jingguanggchen controllingreactionpathwaysofselectivecobondcleavageofglycerol
_version_	1718386961666801664

Controlling reaction pathways of selective C–O bond cleavage of glycerol

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