Photocatalytic CO2 reduction to HCOOH over core-shell Cu@Cu2O catalysts

Photocatalytic conversion of CO2 into HCOOH is a highly anticipated way to address the long-term demand of energy supply. Herein, we report the fabrication of uniform core-shell nanoparticles composed of a Cu core encapsulated by a Cu2O shell by thermal treatment of a Cu-MOF precursor. Impressively,...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Hui Wang, Shijing Cheng, Xiang Cai, Lihua Cheng, Rujin Zhou, Tingting Hou, Yingwei Li
Formato:	article
Lenguaje:	EN
Publicado:	Elsevier 2022
Materias:	Photocatalysis CO2 reduction Plasmon Heterogeneous catalysis Solar energy Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/5a9a7c9e727a43f188cf701647a15622
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:5a9a7c9e727a43f188cf701647a15622
record_format	dspace
spelling	oai:doaj.org-article:5a9a7c9e727a43f188cf701647a156222021-11-28T04:29:20ZPhotocatalytic CO2 reduction to HCOOH over core-shell Cu@Cu2O catalysts1873-390510.1016/j.catcom.2021.106372https://doaj.org/article/5a9a7c9e727a43f188cf701647a156222022-02-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S1566736721000959https://doaj.org/toc/1873-3905Photocatalytic conversion of CO2 into HCOOH is a highly anticipated way to address the long-term demand of energy supply. Herein, we report the fabrication of uniform core-shell nanoparticles composed of a Cu core encapsulated by a Cu2O shell by thermal treatment of a Cu-MOF precursor. Impressively, Cu@Cu2O/C-350 exhibited the catalytic activity in CO2 reduction to HCOOH, attaining a HCOOH production rate of 31 μg/h without any additives at room temperature. Further mechanistic studies indicated that surface Cu2O shell was acted as the active sites for the adsorption and activation of CO2.Hui WangShijing ChengXiang CaiLihua ChengRujin ZhouTingting HouYingwei LiElsevierarticlePhotocatalysisCO2 reductionPlasmonHeterogeneous catalysisSolar energyChemistryQD1-999ENCatalysis Communications, Vol 162, Iss , Pp 106372- (2022)
institution	DOAJ
collection	DOAJ
language	EN
topic	Photocatalysis CO2 reduction Plasmon Heterogeneous catalysis Solar energy Chemistry QD1-999
spellingShingle	Photocatalysis CO2 reduction Plasmon Heterogeneous catalysis Solar energy Chemistry QD1-999 Hui Wang Shijing Cheng Xiang Cai Lihua Cheng Rujin Zhou Tingting Hou Yingwei Li Photocatalytic CO2 reduction to HCOOH over core-shell Cu@Cu2O catalysts
description	Photocatalytic conversion of CO2 into HCOOH is a highly anticipated way to address the long-term demand of energy supply. Herein, we report the fabrication of uniform core-shell nanoparticles composed of a Cu core encapsulated by a Cu2O shell by thermal treatment of a Cu-MOF precursor. Impressively, Cu@Cu2O/C-350 exhibited the catalytic activity in CO2 reduction to HCOOH, attaining a HCOOH production rate of 31 μg/h without any additives at room temperature. Further mechanistic studies indicated that surface Cu2O shell was acted as the active sites for the adsorption and activation of CO2.
format	article
author	Hui Wang Shijing Cheng Xiang Cai Lihua Cheng Rujin Zhou Tingting Hou Yingwei Li
author_facet	Hui Wang Shijing Cheng Xiang Cai Lihua Cheng Rujin Zhou Tingting Hou Yingwei Li
author_sort	Hui Wang
title	Photocatalytic CO2 reduction to HCOOH over core-shell Cu@Cu2O catalysts
title_short	Photocatalytic CO2 reduction to HCOOH over core-shell Cu@Cu2O catalysts
title_full	Photocatalytic CO2 reduction to HCOOH over core-shell Cu@Cu2O catalysts
title_fullStr	Photocatalytic CO2 reduction to HCOOH over core-shell Cu@Cu2O catalysts
title_full_unstemmed	Photocatalytic CO2 reduction to HCOOH over core-shell Cu@Cu2O catalysts
title_sort	photocatalytic co2 reduction to hcooh over core-shell cu@cu2o catalysts
publisher	Elsevier
publishDate	2022
url	https://doaj.org/article/5a9a7c9e727a43f188cf701647a15622
work_keys_str_mv	AT huiwang photocatalyticco2reductiontohcoohovercoreshellcucu2ocatalysts AT shijingcheng photocatalyticco2reductiontohcoohovercoreshellcucu2ocatalysts AT xiangcai photocatalyticco2reductiontohcoohovercoreshellcucu2ocatalysts AT lihuacheng photocatalyticco2reductiontohcoohovercoreshellcucu2ocatalysts AT rujinzhou photocatalyticco2reductiontohcoohovercoreshellcucu2ocatalysts AT tingtinghou photocatalyticco2reductiontohcoohovercoreshellcucu2ocatalysts AT yingweili photocatalyticco2reductiontohcoohovercoreshellcucu2ocatalysts
_version_	1718408379991326720

Photocatalytic CO2 reduction to HCOOH over core-shell Cu@Cu2O catalysts

Ejemplares similares