Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines

Despite their higher abundance, 3d metal-based catalysts are less investigated than their precious metal counterparts. Here, the authors report a cobalt-triphos complex as molecularly-defined non-noble metal catalyst for the reductive amination of carbonyl compounds with gaseous ammonia and hydrogen...

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Autores principales:	Kathiravan Murugesan, Zhihong Wei, Vishwas G. Chandrashekhar, Helfried Neumann, Anke Spannenberg, Haijun Jiao, Matthias Beller, Rajenahally V. Jagadeesh
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/5ab10d284af5402ab16da0d410af6a0e
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spelling	oai:doaj.org-article:5ab10d284af5402ab16da0d410af6a0e2021-12-02T15:35:13ZHomogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines10.1038/s41467-019-13351-72041-1723https://doaj.org/article/5ab10d284af5402ab16da0d410af6a0e2019-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-13351-7https://doaj.org/toc/2041-1723Despite their higher abundance, 3d metal-based catalysts are less investigated than their precious metal counterparts. Here, the authors report a cobalt-triphos complex as molecularly-defined non-noble metal catalyst for the reductive amination of carbonyl compounds with gaseous ammonia and hydrogen.Kathiravan MurugesanZhihong WeiVishwas G. ChandrashekharHelfried NeumannAnke SpannenbergHaijun JiaoMatthias BellerRajenahally V. JagadeeshNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Kathiravan Murugesan Zhihong Wei Vishwas G. Chandrashekhar Helfried Neumann Anke Spannenberg Haijun Jiao Matthias Beller Rajenahally V. Jagadeesh Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines
description	Despite their higher abundance, 3d metal-based catalysts are less investigated than their precious metal counterparts. Here, the authors report a cobalt-triphos complex as molecularly-defined non-noble metal catalyst for the reductive amination of carbonyl compounds with gaseous ammonia and hydrogen.
format	article
author	Kathiravan Murugesan Zhihong Wei Vishwas G. Chandrashekhar Helfried Neumann Anke Spannenberg Haijun Jiao Matthias Beller Rajenahally V. Jagadeesh
author_facet	Kathiravan Murugesan Zhihong Wei Vishwas G. Chandrashekhar Helfried Neumann Anke Spannenberg Haijun Jiao Matthias Beller Rajenahally V. Jagadeesh
author_sort	Kathiravan Murugesan
title	Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines
title_short	Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines
title_full	Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines
title_fullStr	Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines
title_full_unstemmed	Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines
title_sort	homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/5ab10d284af5402ab16da0d410af6a0e
work_keys_str_mv	AT kathiravanmurugesan homogeneouscobaltcatalyzedreductiveaminationforsynthesisoffunctionalizedprimaryamines AT zhihongwei homogeneouscobaltcatalyzedreductiveaminationforsynthesisoffunctionalizedprimaryamines AT vishwasgchandrashekhar homogeneouscobaltcatalyzedreductiveaminationforsynthesisoffunctionalizedprimaryamines AT helfriedneumann homogeneouscobaltcatalyzedreductiveaminationforsynthesisoffunctionalizedprimaryamines AT ankespannenberg homogeneouscobaltcatalyzedreductiveaminationforsynthesisoffunctionalizedprimaryamines AT haijunjiao homogeneouscobaltcatalyzedreductiveaminationforsynthesisoffunctionalizedprimaryamines AT matthiasbeller homogeneouscobaltcatalyzedreductiveaminationforsynthesisoffunctionalizedprimaryamines AT rajenahallyvjagadeesh homogeneouscobaltcatalyzedreductiveaminationforsynthesisoffunctionalizedprimaryamines
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Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines

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