Pd nanoparticles immobilized on MIL-53(Al) as highly effective bifunctional catalysts for oxidation of liquid methanol to methyl formate

Abstract A series of Pd/MIL-53(Al) heterogeneous bifunctional catalysts with different Pd contents were prepared by an impregnation method. The prepared metal–organic frameworks MIL-53(Al) and catalysts were characterized by XRD, SEM, HRTEM, FT-IR and N2 adsorption/desorption techniques. The results...

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Autores principales:	Jian-Fang Liu, Jin-Cheng Mu, Rong-Xian Qin, Sheng-Fu Ji
Formato:	article
Lenguaje:	EN
Publicado:	KeAi Communications Co., Ltd. 2019
Materias:	MIL-53(Al) Pd Bifunctional catalyst Methanol Methyl formate Science Q Petrology QE420-499
Acceso en línea:	https://doaj.org/article/5abb26e76f0a48c38a6e0cc5092245cd
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spelling	oai:doaj.org-article:5abb26e76f0a48c38a6e0cc5092245cd2021-12-02T11:26:20ZPd nanoparticles immobilized on MIL-53(Al) as highly effective bifunctional catalysts for oxidation of liquid methanol to methyl formate10.1007/s12182-019-0334-61672-51071995-8226https://doaj.org/article/5abb26e76f0a48c38a6e0cc5092245cd2019-06-01T00:00:00Zhttp://link.springer.com/article/10.1007/s12182-019-0334-6https://doaj.org/toc/1672-5107https://doaj.org/toc/1995-8226Abstract A series of Pd/MIL-53(Al) heterogeneous bifunctional catalysts with different Pd contents were prepared by an impregnation method. The prepared metal–organic frameworks MIL-53(Al) and catalysts were characterized by XRD, SEM, HRTEM, FT-IR and N2 adsorption/desorption techniques. The results showed that MIL-53(Al) was synthesized successfully, and the structure was unchanged during and after the preparation of the catalysts. The Pd nanoparticles (NPs) with an average particle size of 4.6 nm were uniformly dispersed on the MIL-53(Al). The catalyst exhibited good catalytic activity in the selective oxidation of liquid methanol to methyl formate. Under the conditions of 150 °C, 2 MPa O2 and solvent-free for 5 h, the conversion of methanol could reach 60.3%, and the selectivity of methyl formate was up to 62.2%. In addition, the Pd/MIL-53(Al) bifunctional catalyst exhibited excellent stability and maintained high catalytic activity after five cycles.Jian-Fang LiuJin-Cheng MuRong-Xian QinSheng-Fu JiKeAi Communications Co., Ltd.articleMIL-53(Al)PdBifunctional catalystMethanolMethyl formateScienceQPetrologyQE420-499ENPetroleum Science, Vol 16, Iss 4, Pp 901-911 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	MIL-53(Al) Pd Bifunctional catalyst Methanol Methyl formate Science Q Petrology QE420-499
spellingShingle	MIL-53(Al) Pd Bifunctional catalyst Methanol Methyl formate Science Q Petrology QE420-499 Jian-Fang Liu Jin-Cheng Mu Rong-Xian Qin Sheng-Fu Ji Pd nanoparticles immobilized on MIL-53(Al) as highly effective bifunctional catalysts for oxidation of liquid methanol to methyl formate
description	Abstract A series of Pd/MIL-53(Al) heterogeneous bifunctional catalysts with different Pd contents were prepared by an impregnation method. The prepared metal–organic frameworks MIL-53(Al) and catalysts were characterized by XRD, SEM, HRTEM, FT-IR and N2 adsorption/desorption techniques. The results showed that MIL-53(Al) was synthesized successfully, and the structure was unchanged during and after the preparation of the catalysts. The Pd nanoparticles (NPs) with an average particle size of 4.6 nm were uniformly dispersed on the MIL-53(Al). The catalyst exhibited good catalytic activity in the selective oxidation of liquid methanol to methyl formate. Under the conditions of 150 °C, 2 MPa O2 and solvent-free for 5 h, the conversion of methanol could reach 60.3%, and the selectivity of methyl formate was up to 62.2%. In addition, the Pd/MIL-53(Al) bifunctional catalyst exhibited excellent stability and maintained high catalytic activity after five cycles.
format	article
author	Jian-Fang Liu Jin-Cheng Mu Rong-Xian Qin Sheng-Fu Ji
author_facet	Jian-Fang Liu Jin-Cheng Mu Rong-Xian Qin Sheng-Fu Ji
author_sort	Jian-Fang Liu
title	Pd nanoparticles immobilized on MIL-53(Al) as highly effective bifunctional catalysts for oxidation of liquid methanol to methyl formate
title_short	Pd nanoparticles immobilized on MIL-53(Al) as highly effective bifunctional catalysts for oxidation of liquid methanol to methyl formate
title_full	Pd nanoparticles immobilized on MIL-53(Al) as highly effective bifunctional catalysts for oxidation of liquid methanol to methyl formate
title_fullStr	Pd nanoparticles immobilized on MIL-53(Al) as highly effective bifunctional catalysts for oxidation of liquid methanol to methyl formate
title_full_unstemmed	Pd nanoparticles immobilized on MIL-53(Al) as highly effective bifunctional catalysts for oxidation of liquid methanol to methyl formate
title_sort	pd nanoparticles immobilized on mil-53(al) as highly effective bifunctional catalysts for oxidation of liquid methanol to methyl formate
publisher	KeAi Communications Co., Ltd.
publishDate	2019
url	https://doaj.org/article/5abb26e76f0a48c38a6e0cc5092245cd
work_keys_str_mv	AT jianfangliu pdnanoparticlesimmobilizedonmil53alashighlyeffectivebifunctionalcatalystsforoxidationofliquidmethanoltomethylformate AT jinchengmu pdnanoparticlesimmobilizedonmil53alashighlyeffectivebifunctionalcatalystsforoxidationofliquidmethanoltomethylformate AT rongxianqin pdnanoparticlesimmobilizedonmil53alashighlyeffectivebifunctionalcatalystsforoxidationofliquidmethanoltomethylformate AT shengfuji pdnanoparticlesimmobilizedonmil53alashighlyeffectivebifunctionalcatalystsforoxidationofliquidmethanoltomethylformate
_version_	1718395939530473472

Pd nanoparticles immobilized on MIL-53(Al) as highly effective bifunctional catalysts for oxidation of liquid methanol to methyl formate

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