Evidence for ligand- and solvent-induced disproportionation of uranium(IV)

Disproportion of uranium(IV) is rare, as it is usually the stable product of uranium(III) or (V) disproportionation. Here, the authors report uranium(IV) disproportionation to uranium(III) and (V) revealing ligand and solvent control over a key thermodynamic property of uranium

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Bibliographic Details
Main Authors: Jingzhen Du, Iskander Douair, Erli Lu, John A. Seed, Floriana Tuna, Ashley J. Wooles, Laurent Maron, Stephen T. Liddle
Format: article
Language:EN
Published: Nature Portfolio 2021
Subjects:
Q
Online Access:https://doaj.org/article/5ac34972f56b41e9bc066aa1f726c30f
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Summary:Disproportion of uranium(IV) is rare, as it is usually the stable product of uranium(III) or (V) disproportionation. Here, the authors report uranium(IV) disproportionation to uranium(III) and (V) revealing ligand and solvent control over a key thermodynamic property of uranium