Direct oxygen isotope effect identifies the rate-determining step of electrocatalytic OER at an oxidic surface

Understanding reaction mechanisms is crucial for catalyst design. Here, natural-abundance isotope quantifications of O2 yield mechanistically significant reaction kinetic isotope effects for water oxidation over metal oxide electrodes, the bottleneck step of water electrolysis.

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Autores principales:	Sandra Haschke, Michael Mader, Stefanie Schlicht, André M. Roberts, Alfredo M. Angeles-Boza, Johannes A. C. Barth, Julien Bachmann
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/5b00b716fc6b4038a71204492e7b56ad
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spelling	oai:doaj.org-article:5b00b716fc6b4038a71204492e7b56ad2021-12-02T16:49:54ZDirect oxygen isotope effect identifies the rate-determining step of electrocatalytic OER at an oxidic surface10.1038/s41467-018-07031-12041-1723https://doaj.org/article/5b00b716fc6b4038a71204492e7b56ad2018-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-07031-1https://doaj.org/toc/2041-1723Understanding reaction mechanisms is crucial for catalyst design. Here, natural-abundance isotope quantifications of O2 yield mechanistically significant reaction kinetic isotope effects for water oxidation over metal oxide electrodes, the bottleneck step of water electrolysis.Sandra HaschkeMichael MaderStefanie SchlichtAndré M. RobertsAlfredo M. Angeles-BozaJohannes A. C. BarthJulien BachmannNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Sandra Haschke Michael Mader Stefanie Schlicht André M. Roberts Alfredo M. Angeles-Boza Johannes A. C. Barth Julien Bachmann Direct oxygen isotope effect identifies the rate-determining step of electrocatalytic OER at an oxidic surface
description	Understanding reaction mechanisms is crucial for catalyst design. Here, natural-abundance isotope quantifications of O2 yield mechanistically significant reaction kinetic isotope effects for water oxidation over metal oxide electrodes, the bottleneck step of water electrolysis.
format	article
author	Sandra Haschke Michael Mader Stefanie Schlicht André M. Roberts Alfredo M. Angeles-Boza Johannes A. C. Barth Julien Bachmann
author_facet	Sandra Haschke Michael Mader Stefanie Schlicht André M. Roberts Alfredo M. Angeles-Boza Johannes A. C. Barth Julien Bachmann
author_sort	Sandra Haschke
title	Direct oxygen isotope effect identifies the rate-determining step of electrocatalytic OER at an oxidic surface
title_short	Direct oxygen isotope effect identifies the rate-determining step of electrocatalytic OER at an oxidic surface
title_full	Direct oxygen isotope effect identifies the rate-determining step of electrocatalytic OER at an oxidic surface
title_fullStr	Direct oxygen isotope effect identifies the rate-determining step of electrocatalytic OER at an oxidic surface
title_full_unstemmed	Direct oxygen isotope effect identifies the rate-determining step of electrocatalytic OER at an oxidic surface
title_sort	direct oxygen isotope effect identifies the rate-determining step of electrocatalytic oer at an oxidic surface
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/5b00b716fc6b4038a71204492e7b56ad
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Direct oxygen isotope effect identifies the rate-determining step of electrocatalytic OER at an oxidic surface

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