Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide

Abstract Invited for this month's cover is the group of Viktoria H. Gessner at the Ruhr‐University in Bochum (Germany). The cover shows the structure of the newly reported, isolated metallated ylide. Due to the high negative charge at the ylidic carbon center this compound is „on fire“, but can...

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Autores principales: Mike Jörges, Dr. Alexander Kroll, Leif Kelling, Dr. Richard Gauld, Dr. Bert Mallick, Prof. Dr. Stefan M. Huber, Prof. Dr. Viktoria H. Gessner
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Lenguaje:EN
Publicado: Wiley-VCH 2021
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Acceso en línea:https://doaj.org/article/5b28ae98a5b24e32a26c6d7b43f82ebf
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spelling oai:doaj.org-article:5b28ae98a5b24e32a26c6d7b43f82ebf2021-11-27T06:12:47ZSynthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide2191-136310.1002/open.202100242https://doaj.org/article/5b28ae98a5b24e32a26c6d7b43f82ebf2021-11-01T00:00:00Zhttps://doi.org/10.1002/open.202100242https://doaj.org/toc/2191-1363Abstract Invited for this month's cover is the group of Viktoria H. Gessner at the Ruhr‐University in Bochum (Germany). The cover shows the structure of the newly reported, isolated metallated ylide. Due to the high negative charge at the ylidic carbon center this compound is „on fire“, but can be stabilized by smart molecular design. Structure analyses of the different alkali metal complexes combined with computational studies provide insights into the electronic structure of the compounds Read the full text of their Communication at 10.1002/open.202100187.Mike JörgesDr. Alexander KrollLeif KellingDr. Richard GauldDr. Bert MallickProf. Dr. Stefan M. HuberProf. Dr. Viktoria H. GessnerWiley-VCHarticleChemistryQD1-999ENChemistryOpen, Vol 10, Iss 11, Pp 1088-1088 (2021)
institution DOAJ
collection DOAJ
language EN
topic Chemistry
QD1-999
spellingShingle Chemistry
QD1-999
Mike Jörges
Dr. Alexander Kroll
Leif Kelling
Dr. Richard Gauld
Dr. Bert Mallick
Prof. Dr. Stefan M. Huber
Prof. Dr. Viktoria H. Gessner
Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide
description Abstract Invited for this month's cover is the group of Viktoria H. Gessner at the Ruhr‐University in Bochum (Germany). The cover shows the structure of the newly reported, isolated metallated ylide. Due to the high negative charge at the ylidic carbon center this compound is „on fire“, but can be stabilized by smart molecular design. Structure analyses of the different alkali metal complexes combined with computational studies provide insights into the electronic structure of the compounds Read the full text of their Communication at 10.1002/open.202100187.
format article
author Mike Jörges
Dr. Alexander Kroll
Leif Kelling
Dr. Richard Gauld
Dr. Bert Mallick
Prof. Dr. Stefan M. Huber
Prof. Dr. Viktoria H. Gessner
author_facet Mike Jörges
Dr. Alexander Kroll
Leif Kelling
Dr. Richard Gauld
Dr. Bert Mallick
Prof. Dr. Stefan M. Huber
Prof. Dr. Viktoria H. Gessner
author_sort Mike Jörges
title Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide
title_short Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide
title_full Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide
title_fullStr Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide
title_full_unstemmed Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide
title_sort synthesis, crystal and electronic structures of a thiophosphinoyl‐ and amino‐substituted metallated ylide
publisher Wiley-VCH
publishDate 2021
url https://doaj.org/article/5b28ae98a5b24e32a26c6d7b43f82ebf
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AT leifkelling synthesiscrystalandelectronicstructuresofathiophosphinoylandaminosubstitutedmetallatedylide
AT drrichardgauld synthesiscrystalandelectronicstructuresofathiophosphinoylandaminosubstitutedmetallatedylide
AT drbertmallick synthesiscrystalandelectronicstructuresofathiophosphinoylandaminosubstitutedmetallatedylide
AT profdrstefanmhuber synthesiscrystalandelectronicstructuresofathiophosphinoylandaminosubstitutedmetallatedylide
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