Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide
Abstract Invited for this month's cover is the group of Viktoria H. Gessner at the Ruhr‐University in Bochum (Germany). The cover shows the structure of the newly reported, isolated metallated ylide. Due to the high negative charge at the ylidic carbon center this compound is „on fire“, but can...
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oai:doaj.org-article:5b28ae98a5b24e32a26c6d7b43f82ebf2021-11-27T06:12:47ZSynthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide2191-136310.1002/open.202100242https://doaj.org/article/5b28ae98a5b24e32a26c6d7b43f82ebf2021-11-01T00:00:00Zhttps://doi.org/10.1002/open.202100242https://doaj.org/toc/2191-1363Abstract Invited for this month's cover is the group of Viktoria H. Gessner at the Ruhr‐University in Bochum (Germany). The cover shows the structure of the newly reported, isolated metallated ylide. Due to the high negative charge at the ylidic carbon center this compound is „on fire“, but can be stabilized by smart molecular design. Structure analyses of the different alkali metal complexes combined with computational studies provide insights into the electronic structure of the compounds Read the full text of their Communication at 10.1002/open.202100187.Mike JörgesDr. Alexander KrollLeif KellingDr. Richard GauldDr. Bert MallickProf. Dr. Stefan M. HuberProf. Dr. Viktoria H. GessnerWiley-VCHarticleChemistryQD1-999ENChemistryOpen, Vol 10, Iss 11, Pp 1088-1088 (2021) |
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Chemistry QD1-999 Mike Jörges Dr. Alexander Kroll Leif Kelling Dr. Richard Gauld Dr. Bert Mallick Prof. Dr. Stefan M. Huber Prof. Dr. Viktoria H. Gessner Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide |
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Abstract Invited for this month's cover is the group of Viktoria H. Gessner at the Ruhr‐University in Bochum (Germany). The cover shows the structure of the newly reported, isolated metallated ylide. Due to the high negative charge at the ylidic carbon center this compound is „on fire“, but can be stabilized by smart molecular design. Structure analyses of the different alkali metal complexes combined with computational studies provide insights into the electronic structure of the compounds Read the full text of their Communication at 10.1002/open.202100187. |
format |
article |
author |
Mike Jörges Dr. Alexander Kroll Leif Kelling Dr. Richard Gauld Dr. Bert Mallick Prof. Dr. Stefan M. Huber Prof. Dr. Viktoria H. Gessner |
author_facet |
Mike Jörges Dr. Alexander Kroll Leif Kelling Dr. Richard Gauld Dr. Bert Mallick Prof. Dr. Stefan M. Huber Prof. Dr. Viktoria H. Gessner |
author_sort |
Mike Jörges |
title |
Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide |
title_short |
Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide |
title_full |
Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide |
title_fullStr |
Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide |
title_full_unstemmed |
Synthesis, Crystal and Electronic Structures of a Thiophosphinoyl‐ and Amino‐Substituted Metallated Ylide |
title_sort |
synthesis, crystal and electronic structures of a thiophosphinoyl‐ and amino‐substituted metallated ylide |
publisher |
Wiley-VCH |
publishDate |
2021 |
url |
https://doaj.org/article/5b28ae98a5b24e32a26c6d7b43f82ebf |
work_keys_str_mv |
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