SET activation of nitroarenes by 2-azaallyl anions as a straightforward access to 2,5-dihydro-1,2,4-oxadiazoles

Oxadiazoles are five-membered ring heterocycles comprising an oxygen and two nitrogens, and those with the 1,2,4-oxadiazole skeleton are of interest due to their prevalence in biologically active compounds. Here, the authors report a transition metal-free [3+2]-cycloaddition of nitroarenes with 2-az...

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Autores principales:	Dong Zou, Lishe Gan, Fan Yang, Huan Wang, Youge Pu, Jie Li, Patrick J. Walsh
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/5bb0184a7bbf4be48254a8a86047300c
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spelling	oai:doaj.org-article:5bb0184a7bbf4be48254a8a86047300c2021-12-05T12:22:04ZSET activation of nitroarenes by 2-azaallyl anions as a straightforward access to 2,5-dihydro-1,2,4-oxadiazoles10.1038/s41467-021-26767-x2041-1723https://doaj.org/article/5bb0184a7bbf4be48254a8a86047300c2021-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-26767-xhttps://doaj.org/toc/2041-1723Oxadiazoles are five-membered ring heterocycles comprising an oxygen and two nitrogens, and those with the 1,2,4-oxadiazole skeleton are of interest due to their prevalence in biologically active compounds. Here, the authors report a transition metal-free [3+2]-cycloaddition of nitroarenes with 2-azaallyl anions under basic conditions to access 2,5-dihydro-1,2,4-oxadiazoles.Dong ZouLishe GanFan YangHuan WangYouge PuJie LiPatrick J. WalshNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-10 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Dong Zou Lishe Gan Fan Yang Huan Wang Youge Pu Jie Li Patrick J. Walsh SET activation of nitroarenes by 2-azaallyl anions as a straightforward access to 2,5-dihydro-1,2,4-oxadiazoles
description	Oxadiazoles are five-membered ring heterocycles comprising an oxygen and two nitrogens, and those with the 1,2,4-oxadiazole skeleton are of interest due to their prevalence in biologically active compounds. Here, the authors report a transition metal-free [3+2]-cycloaddition of nitroarenes with 2-azaallyl anions under basic conditions to access 2,5-dihydro-1,2,4-oxadiazoles.
format	article
author	Dong Zou Lishe Gan Fan Yang Huan Wang Youge Pu Jie Li Patrick J. Walsh
author_facet	Dong Zou Lishe Gan Fan Yang Huan Wang Youge Pu Jie Li Patrick J. Walsh
author_sort	Dong Zou
title	SET activation of nitroarenes by 2-azaallyl anions as a straightforward access to 2,5-dihydro-1,2,4-oxadiazoles
title_short	SET activation of nitroarenes by 2-azaallyl anions as a straightforward access to 2,5-dihydro-1,2,4-oxadiazoles
title_full	SET activation of nitroarenes by 2-azaallyl anions as a straightforward access to 2,5-dihydro-1,2,4-oxadiazoles
title_fullStr	SET activation of nitroarenes by 2-azaallyl anions as a straightforward access to 2,5-dihydro-1,2,4-oxadiazoles
title_full_unstemmed	SET activation of nitroarenes by 2-azaallyl anions as a straightforward access to 2,5-dihydro-1,2,4-oxadiazoles
title_sort	set activation of nitroarenes by 2-azaallyl anions as a straightforward access to 2,5-dihydro-1,2,4-oxadiazoles
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/5bb0184a7bbf4be48254a8a86047300c
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SET activation of nitroarenes by 2-azaallyl anions as a straightforward access to 2,5-dihydro-1,2,4-oxadiazoles

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