Chemodivergent assembly of ortho-functionalized phenols with tunable selectivity via rhodium(III)-catalyzed and solvent-controlled C-H activation
Ortho functionalisation of phenols can be achieved using N-phenoxy amide directing groups. Here a method for chemodivergent C-H alkenylation, alkylation, carboetherification, or [3 + 2] annulation is presented, with product selectivity determined by the choice of solvent.
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Nature Portfolio
2021
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oai:doaj.org-article:5c42cf4a39ce47299fc463dd179e42df2021-12-02T15:02:47ZChemodivergent assembly of ortho-functionalized phenols with tunable selectivity via rhodium(III)-catalyzed and solvent-controlled C-H activation10.1038/s42004-021-00518-x2399-3669https://doaj.org/article/5c42cf4a39ce47299fc463dd179e42df2021-06-01T00:00:00Zhttps://doi.org/10.1038/s42004-021-00518-xhttps://doaj.org/toc/2399-3669Ortho functionalisation of phenols can be achieved using N-phenoxy amide directing groups. Here a method for chemodivergent C-H alkenylation, alkylation, carboetherification, or [3 + 2] annulation is presented, with product selectivity determined by the choice of solvent.Haiman ZhangShuang LinHui GaoKaixin ZhangYi WangZhi ZhouWei YiNature PortfolioarticleChemistryQD1-999ENCommunications Chemistry, Vol 4, Iss 1, Pp 1-12 (2021) |
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DOAJ |
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DOAJ |
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EN |
| topic |
Chemistry QD1-999 |
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Chemistry QD1-999 Haiman Zhang Shuang Lin Hui Gao Kaixin Zhang Yi Wang Zhi Zhou Wei Yi Chemodivergent assembly of ortho-functionalized phenols with tunable selectivity via rhodium(III)-catalyzed and solvent-controlled C-H activation |
| description |
Ortho functionalisation of phenols can be achieved using N-phenoxy amide directing groups. Here a method for chemodivergent C-H alkenylation, alkylation, carboetherification, or [3 + 2] annulation is presented, with product selectivity determined by the choice of solvent. |
| format |
article |
| author |
Haiman Zhang Shuang Lin Hui Gao Kaixin Zhang Yi Wang Zhi Zhou Wei Yi |
| author_facet |
Haiman Zhang Shuang Lin Hui Gao Kaixin Zhang Yi Wang Zhi Zhou Wei Yi |
| author_sort |
Haiman Zhang |
| title |
Chemodivergent assembly of ortho-functionalized phenols with tunable selectivity via rhodium(III)-catalyzed and solvent-controlled C-H activation |
| title_short |
Chemodivergent assembly of ortho-functionalized phenols with tunable selectivity via rhodium(III)-catalyzed and solvent-controlled C-H activation |
| title_full |
Chemodivergent assembly of ortho-functionalized phenols with tunable selectivity via rhodium(III)-catalyzed and solvent-controlled C-H activation |
| title_fullStr |
Chemodivergent assembly of ortho-functionalized phenols with tunable selectivity via rhodium(III)-catalyzed and solvent-controlled C-H activation |
| title_full_unstemmed |
Chemodivergent assembly of ortho-functionalized phenols with tunable selectivity via rhodium(III)-catalyzed and solvent-controlled C-H activation |
| title_sort |
chemodivergent assembly of ortho-functionalized phenols with tunable selectivity via rhodium(iii)-catalyzed and solvent-controlled c-h activation |
| publisher |
Nature Portfolio |
| publishDate |
2021 |
| url |
https://doaj.org/article/5c42cf4a39ce47299fc463dd179e42df |
| work_keys_str_mv |
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| _version_ |
1718389079072047104 |