Dimercaptosuccinic Acid Functionalized Polystyrene Column for Trace Concentration Determination of Heavy Metal Ions: Experimental and Theoretical Calculation Studies

Metal ion studies in wastewater are required on a regular basis for environmental monitoring and assessment. Less metal ion concentrations and the interference from complex sample matrices remains challenging for instrumental quantification. Herein, we proposed a fix-bed solid phase extraction metho...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Uzma Haseen, Syed Ghazanfar Ali, Khalid Umar, Abuzer Ali, Hilal Ahmad, Haris Manzoor Khan
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	toxicity extraction trace metal ions spectroscopy density functional theory Hydraulic engineering TC1-978 Water supply for domestic and industrial purposes TD201-500
Acceso en línea:	https://doaj.org/article/5c56d95109b844dda7d33b323e45c7cc
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:5c56d95109b844dda7d33b323e45c7cc
record_format	dspace
spelling	oai:doaj.org-article:5c56d95109b844dda7d33b323e45c7cc2021-11-11T19:55:58ZDimercaptosuccinic Acid Functionalized Polystyrene Column for Trace Concentration Determination of Heavy Metal Ions: Experimental and Theoretical Calculation Studies10.3390/w132130562073-4441https://doaj.org/article/5c56d95109b844dda7d33b323e45c7cc2021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4441/13/21/3056https://doaj.org/toc/2073-4441Metal ion studies in wastewater are required on a regular basis for environmental monitoring and assessment. Less metal ion concentrations and the interference from complex sample matrices remains challenging for instrumental quantification. Herein, we proposed a fix-bed solid phase extraction method, consisting of a newly prepared dimercaptosuccinic acid functionalized polystyrene beads. The ligand forms stable complex with Hg(II), Pb(II), and Cd(II), evident by experimental as well as density functional theory. The metal-ligand stabilization energy calculations, suggested the higher selectivity of polystyrene dimercaptosuccinic acid (PSDMSA) toward Pb(II) compared to Cd(II) and Hg(II). The prepared adsorbent was utilized to enrich Hg(II), Pb(II), and Cd(II) ions from environmental samples. Column parameters were studied in detail and optimized accordingly. The preconcentration factor for Hg(II), Pb(II), and Cd(II) were found to be 900, with the preconcentration limit of 0.74 µg L<sup>−1</sup>. The detection limit for Pb(II), Cd(II), and Hg(II) ions was found to be 1.3 ± 0.2, 1.5 ± 0.3, and 1.8 ± 0.3 ng L<sup>−1</sup>, respectively. The method accuracy was tested against systematic and continuous errors by standard addition method (<5% RSD). Real samples was successfully analyzed following the proposed method.Uzma HaseenSyed Ghazanfar AliKhalid UmarAbuzer AliHilal AhmadHaris Manzoor KhanMDPI AGarticletoxicityextractiontrace metal ionsspectroscopydensity functional theoryHydraulic engineeringTC1-978Water supply for domestic and industrial purposesTD201-500ENWater, Vol 13, Iss 3056, p 3056 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	toxicity extraction trace metal ions spectroscopy density functional theory Hydraulic engineering TC1-978 Water supply for domestic and industrial purposes TD201-500
spellingShingle	toxicity extraction trace metal ions spectroscopy density functional theory Hydraulic engineering TC1-978 Water supply for domestic and industrial purposes TD201-500 Uzma Haseen Syed Ghazanfar Ali Khalid Umar Abuzer Ali Hilal Ahmad Haris Manzoor Khan Dimercaptosuccinic Acid Functionalized Polystyrene Column for Trace Concentration Determination of Heavy Metal Ions: Experimental and Theoretical Calculation Studies
description	Metal ion studies in wastewater are required on a regular basis for environmental monitoring and assessment. Less metal ion concentrations and the interference from complex sample matrices remains challenging for instrumental quantification. Herein, we proposed a fix-bed solid phase extraction method, consisting of a newly prepared dimercaptosuccinic acid functionalized polystyrene beads. The ligand forms stable complex with Hg(II), Pb(II), and Cd(II), evident by experimental as well as density functional theory. The metal-ligand stabilization energy calculations, suggested the higher selectivity of polystyrene dimercaptosuccinic acid (PSDMSA) toward Pb(II) compared to Cd(II) and Hg(II). The prepared adsorbent was utilized to enrich Hg(II), Pb(II), and Cd(II) ions from environmental samples. Column parameters were studied in detail and optimized accordingly. The preconcentration factor for Hg(II), Pb(II), and Cd(II) were found to be 900, with the preconcentration limit of 0.74 µg L<sup>−1</sup>. The detection limit for Pb(II), Cd(II), and Hg(II) ions was found to be 1.3 ± 0.2, 1.5 ± 0.3, and 1.8 ± 0.3 ng L<sup>−1</sup>, respectively. The method accuracy was tested against systematic and continuous errors by standard addition method (<5% RSD). Real samples was successfully analyzed following the proposed method.
format	article
author	Uzma Haseen Syed Ghazanfar Ali Khalid Umar Abuzer Ali Hilal Ahmad Haris Manzoor Khan
author_facet	Uzma Haseen Syed Ghazanfar Ali Khalid Umar Abuzer Ali Hilal Ahmad Haris Manzoor Khan
author_sort	Uzma Haseen
title	Dimercaptosuccinic Acid Functionalized Polystyrene Column for Trace Concentration Determination of Heavy Metal Ions: Experimental and Theoretical Calculation Studies
title_short	Dimercaptosuccinic Acid Functionalized Polystyrene Column for Trace Concentration Determination of Heavy Metal Ions: Experimental and Theoretical Calculation Studies
title_full	Dimercaptosuccinic Acid Functionalized Polystyrene Column for Trace Concentration Determination of Heavy Metal Ions: Experimental and Theoretical Calculation Studies
title_fullStr	Dimercaptosuccinic Acid Functionalized Polystyrene Column for Trace Concentration Determination of Heavy Metal Ions: Experimental and Theoretical Calculation Studies
title_full_unstemmed	Dimercaptosuccinic Acid Functionalized Polystyrene Column for Trace Concentration Determination of Heavy Metal Ions: Experimental and Theoretical Calculation Studies
title_sort	dimercaptosuccinic acid functionalized polystyrene column for trace concentration determination of heavy metal ions: experimental and theoretical calculation studies
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/5c56d95109b844dda7d33b323e45c7cc
work_keys_str_mv	AT uzmahaseen dimercaptosuccinicacidfunctionalizedpolystyrenecolumnfortraceconcentrationdeterminationofheavymetalionsexperimentalandtheoreticalcalculationstudies AT syedghazanfarali dimercaptosuccinicacidfunctionalizedpolystyrenecolumnfortraceconcentrationdeterminationofheavymetalionsexperimentalandtheoreticalcalculationstudies AT khalidumar dimercaptosuccinicacidfunctionalizedpolystyrenecolumnfortraceconcentrationdeterminationofheavymetalionsexperimentalandtheoreticalcalculationstudies AT abuzerali dimercaptosuccinicacidfunctionalizedpolystyrenecolumnfortraceconcentrationdeterminationofheavymetalionsexperimentalandtheoreticalcalculationstudies AT hilalahmad dimercaptosuccinicacidfunctionalizedpolystyrenecolumnfortraceconcentrationdeterminationofheavymetalionsexperimentalandtheoreticalcalculationstudies AT harismanzoorkhan dimercaptosuccinicacidfunctionalizedpolystyrenecolumnfortraceconcentrationdeterminationofheavymetalionsexperimentalandtheoreticalcalculationstudies
_version_	1718431350319480832

Dimercaptosuccinic Acid Functionalized Polystyrene Column for Trace Concentration Determination of Heavy Metal Ions: Experimental and Theoretical Calculation Studies

Ejemplares similares