Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid

Designing catalysts and understanding the influence of ligands for particular transformations remains a highly challenging task. Here, the authors show that bisphosphine ligands can alter the geometry of the active site in silver catalysts, driving protonation and ultimately extrusion of carbon diox...

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Autores principales:	Athanasios Zavras, George N. Khairallah, Marjan Krstić, Marion Girod, Steven Daly, Rodolphe Antoine, Philippe Maitre, Roger J. Mulder, Stefanie-Ann Alexander, Vlasta Bonačić-Koutecký, Philippe Dugourd, Richard A. J. O’Hair
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/5c9942ddd8b84c90bbfe868edef555cf
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spelling	oai:doaj.org-article:5c9942ddd8b84c90bbfe868edef555cf2021-12-02T16:57:49ZLigand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid10.1038/ncomms117462041-1723https://doaj.org/article/5c9942ddd8b84c90bbfe868edef555cf2016-06-01T00:00:00Zhttps://doi.org/10.1038/ncomms11746https://doaj.org/toc/2041-1723Designing catalysts and understanding the influence of ligands for particular transformations remains a highly challenging task. Here, the authors show that bisphosphine ligands can alter the geometry of the active site in silver catalysts, driving protonation and ultimately extrusion of carbon dioxide from formic acid.Athanasios ZavrasGeorge N. KhairallahMarjan KrstićMarion GirodSteven DalyRodolphe AntoinePhilippe MaitreRoger J. MulderStefanie-Ann AlexanderVlasta Bonačić-KouteckýPhilippe DugourdRichard A. J. O’HairNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-8 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Athanasios Zavras George N. Khairallah Marjan Krstić Marion Girod Steven Daly Rodolphe Antoine Philippe Maitre Roger J. Mulder Stefanie-Ann Alexander Vlasta Bonačić-Koutecký Philippe Dugourd Richard A. J. O’Hair Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid
description	Designing catalysts and understanding the influence of ligands for particular transformations remains a highly challenging task. Here, the authors show that bisphosphine ligands can alter the geometry of the active site in silver catalysts, driving protonation and ultimately extrusion of carbon dioxide from formic acid.
format	article
author	Athanasios Zavras George N. Khairallah Marjan Krstić Marion Girod Steven Daly Rodolphe Antoine Philippe Maitre Roger J. Mulder Stefanie-Ann Alexander Vlasta Bonačić-Koutecký Philippe Dugourd Richard A. J. O’Hair
author_facet	Athanasios Zavras George N. Khairallah Marjan Krstić Marion Girod Steven Daly Rodolphe Antoine Philippe Maitre Roger J. Mulder Stefanie-Ann Alexander Vlasta Bonačić-Koutecký Philippe Dugourd Richard A. J. O’Hair
author_sort	Athanasios Zavras
title	Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid
title_short	Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid
title_full	Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid
title_fullStr	Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid
title_full_unstemmed	Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid
title_sort	ligand-induced substrate steering and reshaping of [ag2(h)]+ scaffold for selective co2 extrusion from formic acid
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/5c9942ddd8b84c90bbfe868edef555cf
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Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid

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