Controlled synthesis of various Fe2O3 morphologies as energy storage materials

Abstract Air pollution from vehicle emissions is a major problem in developing countries. Consequently, the use of iron-based rechargeable batteries, which is an effective method of reducing air pollution, have been extensively studied for electric vehicles. The structures and morphologies of iron p...

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Autores principales: Bui Thi Hang, Trinh Tuan Anh
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Lenguaje:EN
Publicado: Nature Portfolio 2021
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spelling oai:doaj.org-article:5cb1cf5dc59d407eb2a284be689d1c4e2021-12-02T13:35:03ZControlled synthesis of various Fe2O3 morphologies as energy storage materials10.1038/s41598-021-84755-z2045-2322https://doaj.org/article/5cb1cf5dc59d407eb2a284be689d1c4e2021-03-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-84755-zhttps://doaj.org/toc/2045-2322Abstract Air pollution from vehicle emissions is a major problem in developing countries. Consequently, the use of iron-based rechargeable batteries, which is an effective method of reducing air pollution, have been extensively studied for electric vehicles. The structures and morphologies of iron particles significantly affect the cycle performance of iron-based rechargeable batteries. The synthesis parameters for these iron materials also remarkably influence their structures, shapes, sizes, and electrochemical properties. In this study, we fabricated α-Fe2O3 materials with various shapes and sizes via a facile hydrothermal route and investigated the effects of raw materials on their structures, morphologies, and properties. The structural characteristics of the synthesized iron oxides were studied via X-ray diffraction using scanning electron microscopy. Results indicate that changing the concentration of raw materials modified the structure and morphology of the synthesized α-Fe2O3 particles, that is, the desired shape and size of α-Fe2O3 can be controlled. The effects of the structure and morphology of α-Fe2O3 particles on their electrochemical characteristics were investigated. The results show that the morphology and shape of the iron oxide particles remarkably affected the redox reaction rate and discharge capacity of the Fe2O3/C composite electrodes. Among the synthesized α-Fe2O3 materials, the cubic-shaped α-Fe2O3 exhibited the highest discharge capacity. This material is a potential candidate for application in iron-based aqueous batteries. Our results may facilitate not only the controlled synthesis of α-Fe2O3 nanoparticles for potential technical applications but also the production of electrode materials with high capacity and good cycle performance for iron-based rechargeable batteries.Bui Thi HangTrinh Tuan AnhNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-10 (2021)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Bui Thi Hang
Trinh Tuan Anh
Controlled synthesis of various Fe2O3 morphologies as energy storage materials
description Abstract Air pollution from vehicle emissions is a major problem in developing countries. Consequently, the use of iron-based rechargeable batteries, which is an effective method of reducing air pollution, have been extensively studied for electric vehicles. The structures and morphologies of iron particles significantly affect the cycle performance of iron-based rechargeable batteries. The synthesis parameters for these iron materials also remarkably influence their structures, shapes, sizes, and electrochemical properties. In this study, we fabricated α-Fe2O3 materials with various shapes and sizes via a facile hydrothermal route and investigated the effects of raw materials on their structures, morphologies, and properties. The structural characteristics of the synthesized iron oxides were studied via X-ray diffraction using scanning electron microscopy. Results indicate that changing the concentration of raw materials modified the structure and morphology of the synthesized α-Fe2O3 particles, that is, the desired shape and size of α-Fe2O3 can be controlled. The effects of the structure and morphology of α-Fe2O3 particles on their electrochemical characteristics were investigated. The results show that the morphology and shape of the iron oxide particles remarkably affected the redox reaction rate and discharge capacity of the Fe2O3/C composite electrodes. Among the synthesized α-Fe2O3 materials, the cubic-shaped α-Fe2O3 exhibited the highest discharge capacity. This material is a potential candidate for application in iron-based aqueous batteries. Our results may facilitate not only the controlled synthesis of α-Fe2O3 nanoparticles for potential technical applications but also the production of electrode materials with high capacity and good cycle performance for iron-based rechargeable batteries.
format article
author Bui Thi Hang
Trinh Tuan Anh
author_facet Bui Thi Hang
Trinh Tuan Anh
author_sort Bui Thi Hang
title Controlled synthesis of various Fe2O3 morphologies as energy storage materials
title_short Controlled synthesis of various Fe2O3 morphologies as energy storage materials
title_full Controlled synthesis of various Fe2O3 morphologies as energy storage materials
title_fullStr Controlled synthesis of various Fe2O3 morphologies as energy storage materials
title_full_unstemmed Controlled synthesis of various Fe2O3 morphologies as energy storage materials
title_sort controlled synthesis of various fe2o3 morphologies as energy storage materials
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/5cb1cf5dc59d407eb2a284be689d1c4e
work_keys_str_mv AT buithihang controlledsynthesisofvariousfe2o3morphologiesasenergystoragematerials
AT trinhtuananh controlledsynthesisofvariousfe2o3morphologiesasenergystoragematerials
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