Role of solvent-anion charge transfer in oxidative degradation of battery electrolytes

Based on computations, the authors show that voltage stability of battery electrolytes is determined not by a single component but by formation of charge transfer complexes between salt anions and solvent molecules. A physical model is proposed and validated on several common electrolyte composition...

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Autores principales:	Eric R. Fadel, Francesco Faglioni, Georgy Samsonidze, Nicola Molinari, Boris V. Merinov, William A. Goddard III, Jeffrey C. Grossman, Jonathan P. Mailoa, Boris Kozinsky
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/5d258882f98244a2a92450d83fa39d1b
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spelling	oai:doaj.org-article:5d258882f98244a2a92450d83fa39d1b2021-12-02T17:32:09ZRole of solvent-anion charge transfer in oxidative degradation of battery electrolytes10.1038/s41467-019-11317-32041-1723https://doaj.org/article/5d258882f98244a2a92450d83fa39d1b2019-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-11317-3https://doaj.org/toc/2041-1723Based on computations, the authors show that voltage stability of battery electrolytes is determined not by a single component but by formation of charge transfer complexes between salt anions and solvent molecules. A physical model is proposed and validated on several common electrolyte compositions.Eric R. FadelFrancesco FaglioniGeorgy SamsonidzeNicola MolinariBoris V. MerinovWilliam A. Goddard IIIJeffrey C. GrossmanJonathan P. MailoaBoris KozinskyNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Eric R. Fadel Francesco Faglioni Georgy Samsonidze Nicola Molinari Boris V. Merinov William A. Goddard III Jeffrey C. Grossman Jonathan P. Mailoa Boris Kozinsky Role of solvent-anion charge transfer in oxidative degradation of battery electrolytes
description	Based on computations, the authors show that voltage stability of battery electrolytes is determined not by a single component but by formation of charge transfer complexes between salt anions and solvent molecules. A physical model is proposed and validated on several common electrolyte compositions.
format	article
author	Eric R. Fadel Francesco Faglioni Georgy Samsonidze Nicola Molinari Boris V. Merinov William A. Goddard III Jeffrey C. Grossman Jonathan P. Mailoa Boris Kozinsky
author_facet	Eric R. Fadel Francesco Faglioni Georgy Samsonidze Nicola Molinari Boris V. Merinov William A. Goddard III Jeffrey C. Grossman Jonathan P. Mailoa Boris Kozinsky
author_sort	Eric R. Fadel
title	Role of solvent-anion charge transfer in oxidative degradation of battery electrolytes
title_short	Role of solvent-anion charge transfer in oxidative degradation of battery electrolytes
title_full	Role of solvent-anion charge transfer in oxidative degradation of battery electrolytes
title_fullStr	Role of solvent-anion charge transfer in oxidative degradation of battery electrolytes
title_full_unstemmed	Role of solvent-anion charge transfer in oxidative degradation of battery electrolytes
title_sort	role of solvent-anion charge transfer in oxidative degradation of battery electrolytes
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/5d258882f98244a2a92450d83fa39d1b
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Role of solvent-anion charge transfer in oxidative degradation of battery electrolytes

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