L-Lysine-assisted solvothermal synthesis of hollow-like structure LiFePO4/C powders as cathode materials for Li-ion batteries

LiFePO4/C powders were synthesized by solvothermal method using L-Lysine as a surfactant for controlling over the particle size and shape. The effects of L-Lysine contents on the phase, structure, microstructure, and electrochemical properties were studied by X-ray diffractometry, scanning electron...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	A. Sarmadi, S.M. Masoudpanah, S. Alamolhoda
Formato:	article
Lenguaje:	EN
Publicado:	Elsevier 2021
Materias:	LiFePO4 Solvothermal synthesis L-Lysine Hollow-like structure Electrochemical properties Mining engineering. Metallurgy TN1-997
Acceso en línea:	https://doaj.org/article/5debde3c36104fe7875fd584e6dacaea
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:5debde3c36104fe7875fd584e6dacaea
record_format	dspace
spelling	oai:doaj.org-article:5debde3c36104fe7875fd584e6dacaea2021-11-20T05:06:37ZL-Lysine-assisted solvothermal synthesis of hollow-like structure LiFePO4/C powders as cathode materials for Li-ion batteries2238-785410.1016/j.jmrt.2021.11.002https://doaj.org/article/5debde3c36104fe7875fd584e6dacaea2021-11-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2238785421012813https://doaj.org/toc/2238-7854LiFePO4/C powders were synthesized by solvothermal method using L-Lysine as a surfactant for controlling over the particle size and shape. The effects of L-Lysine contents on the phase, structure, microstructure, and electrochemical properties were studied by X-ray diffractometry, scanning electron microscopy, infrared spectroscopy, galvanic charge/discharge, and electrochemical impedance spectroscopy methods. As the amount of L-Lysine increased, the large sheet-like morphology was transformed to the spherical particulate and hollow-like structure. The LiFePO4/C powder obtained by 50 mmol L-Lysine showed the highest specific capacity of 96 mAh g−1 at 1C rate and high capacity retention of 95.6% following 650 cycles because of the low antisite defects and particulate morphology of LiFePO4. Moreover, the high rate capability of the LiFePO4/C powders was attributed to their small spherical particles and hollow-like structure, leading to the high electrochemical kinetics as investigated by electrochemical impedance spectroscopy.A. SarmadiS.M. MasoudpanahS. AlamolhodaElsevierarticleLiFePO4Solvothermal synthesisL-LysineHollow-like structureElectrochemical propertiesMining engineering. MetallurgyTN1-997ENJournal of Materials Research and Technology, Vol 15, Iss , Pp 5405-5413 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	LiFePO4 Solvothermal synthesis L-Lysine Hollow-like structure Electrochemical properties Mining engineering. Metallurgy TN1-997
spellingShingle	LiFePO4 Solvothermal synthesis L-Lysine Hollow-like structure Electrochemical properties Mining engineering. Metallurgy TN1-997 A. Sarmadi S.M. Masoudpanah S. Alamolhoda L-Lysine-assisted solvothermal synthesis of hollow-like structure LiFePO4/C powders as cathode materials for Li-ion batteries
description	LiFePO4/C powders were synthesized by solvothermal method using L-Lysine as a surfactant for controlling over the particle size and shape. The effects of L-Lysine contents on the phase, structure, microstructure, and electrochemical properties were studied by X-ray diffractometry, scanning electron microscopy, infrared spectroscopy, galvanic charge/discharge, and electrochemical impedance spectroscopy methods. As the amount of L-Lysine increased, the large sheet-like morphology was transformed to the spherical particulate and hollow-like structure. The LiFePO4/C powder obtained by 50 mmol L-Lysine showed the highest specific capacity of 96 mAh g−1 at 1C rate and high capacity retention of 95.6% following 650 cycles because of the low antisite defects and particulate morphology of LiFePO4. Moreover, the high rate capability of the LiFePO4/C powders was attributed to their small spherical particles and hollow-like structure, leading to the high electrochemical kinetics as investigated by electrochemical impedance spectroscopy.
format	article
author	A. Sarmadi S.M. Masoudpanah S. Alamolhoda
author_facet	A. Sarmadi S.M. Masoudpanah S. Alamolhoda
author_sort	A. Sarmadi
title	L-Lysine-assisted solvothermal synthesis of hollow-like structure LiFePO4/C powders as cathode materials for Li-ion batteries
title_short	L-Lysine-assisted solvothermal synthesis of hollow-like structure LiFePO4/C powders as cathode materials for Li-ion batteries
title_full	L-Lysine-assisted solvothermal synthesis of hollow-like structure LiFePO4/C powders as cathode materials for Li-ion batteries
title_fullStr	L-Lysine-assisted solvothermal synthesis of hollow-like structure LiFePO4/C powders as cathode materials for Li-ion batteries
title_full_unstemmed	L-Lysine-assisted solvothermal synthesis of hollow-like structure LiFePO4/C powders as cathode materials for Li-ion batteries
title_sort	l-lysine-assisted solvothermal synthesis of hollow-like structure lifepo4/c powders as cathode materials for li-ion batteries
publisher	Elsevier
publishDate	2021
url	https://doaj.org/article/5debde3c36104fe7875fd584e6dacaea
work_keys_str_mv	AT asarmadi llysineassistedsolvothermalsynthesisofhollowlikestructurelifepo4cpowdersascathodematerialsforliionbatteries AT smmasoudpanah llysineassistedsolvothermalsynthesisofhollowlikestructurelifepo4cpowdersascathodematerialsforliionbatteries AT salamolhoda llysineassistedsolvothermalsynthesisofhollowlikestructurelifepo4cpowdersascathodematerialsforliionbatteries
_version_	1718419599602483200

L-Lysine-assisted solvothermal synthesis of hollow-like structure LiFePO4/C powders as cathode materials for Li-ion batteries

Ejemplares similares