Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms
Despite their importance as mechanistic models for Haber Bosch ammonia synthesis from N2 and H2, high oxidation state terminal metal-nitrides are notoriously unreactive towards H2. Here, the authors report hydrogenolysis of a uranium(V)-nitride, which can occur directly or by Frustrated Lewis Pair c...
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| Main Authors: | , , , , , , , , |
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| Format: | article |
| Language: | EN |
| Published: |
Nature Portfolio
2020
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| Subjects: | |
| Online Access: | https://doaj.org/article/5df857d1db1b4e86b69d7903c71b4111 |
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| Summary: | Despite their importance as mechanistic models for Haber Bosch ammonia synthesis from N2 and H2, high oxidation state terminal metal-nitrides are notoriously unreactive towards H2. Here, the authors report hydrogenolysis of a uranium(V)-nitride, which can occur directly or by Frustrated Lewis Pair chemistry with a borane ancillary. |
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