Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms

Despite their importance as mechanistic models for Haber Bosch ammonia synthesis from N2 and H2, high oxidation state terminal metal-nitrides are notoriously unreactive towards H2. Here, the authors report hydrogenolysis of a uranium(V)-nitride, which can occur directly or by Frustrated Lewis Pair c...

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Autores principales:	Lucile Chatelain, Elisa Louyriac, Iskander Douair, Erli Lu, Floriana Tuna, Ashley J. Wooles, Benedict M. Gardner, Laurent Maron, Stephen T. Liddle
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/5df857d1db1b4e86b69d7903c71b4111
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spelling	oai:doaj.org-article:5df857d1db1b4e86b69d7903c71b41112021-12-02T15:33:31ZTerminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms10.1038/s41467-019-14221-y2041-1723https://doaj.org/article/5df857d1db1b4e86b69d7903c71b41112020-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-14221-yhttps://doaj.org/toc/2041-1723Despite their importance as mechanistic models for Haber Bosch ammonia synthesis from N2 and H2, high oxidation state terminal metal-nitrides are notoriously unreactive towards H2. Here, the authors report hydrogenolysis of a uranium(V)-nitride, which can occur directly or by Frustrated Lewis Pair chemistry with a borane ancillary.Lucile ChatelainElisa LouyriacIskander DouairErli LuFloriana TunaAshley J. WoolesBenedict M. GardnerLaurent MaronStephen T. LiddleNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-12 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Lucile Chatelain Elisa Louyriac Iskander Douair Erli Lu Floriana Tuna Ashley J. Wooles Benedict M. Gardner Laurent Maron Stephen T. Liddle Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms
description	Despite their importance as mechanistic models for Haber Bosch ammonia synthesis from N2 and H2, high oxidation state terminal metal-nitrides are notoriously unreactive towards H2. Here, the authors report hydrogenolysis of a uranium(V)-nitride, which can occur directly or by Frustrated Lewis Pair chemistry with a borane ancillary.
format	article
author	Lucile Chatelain Elisa Louyriac Iskander Douair Erli Lu Floriana Tuna Ashley J. Wooles Benedict M. Gardner Laurent Maron Stephen T. Liddle
author_facet	Lucile Chatelain Elisa Louyriac Iskander Douair Erli Lu Floriana Tuna Ashley J. Wooles Benedict M. Gardner Laurent Maron Stephen T. Liddle
author_sort	Lucile Chatelain
title	Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms
title_short	Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms
title_full	Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms
title_fullStr	Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms
title_full_unstemmed	Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms
title_sort	terminal uranium(v)-nitride hydrogenations involving direct addition or frustrated lewis pair mechanisms
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/5df857d1db1b4e86b69d7903c71b4111
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Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms

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