Complex barite filter cake removal using in-situ generated acids by thermochemicals
Abstract In sandstone formations, the quartz particles integrate with drilling fluid solids and become part of the filter cake structure. As a result, the dissolution rate of the filter cake diminishes and reduces the removal efficiency. This paper presents a novel solution to overcome the challenge...
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2020
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oai:doaj.org-article:5e6f2903f0fe4802896c35fb2d98dee52021-12-02T18:48:22ZComplex barite filter cake removal using in-situ generated acids by thermochemicals10.1038/s41598-020-72858-y2045-2322https://doaj.org/article/5e6f2903f0fe4802896c35fb2d98dee52020-09-01T00:00:00Zhttps://doi.org/10.1038/s41598-020-72858-yhttps://doaj.org/toc/2045-2322Abstract In sandstone formations, the quartz particles integrate with drilling fluid solids and become part of the filter cake structure. As a result, the dissolution rate of the filter cake diminishes and reduces the removal efficiency. This paper presents a novel solution to overcome the challenges that restricts the filter cake removal process such as the presence of the quartz layer and the polymer coat. A multi-stage method for removing the filter cake from a wellbore is presented. The composition of the new formulation is; ammonium fluoride (NH4F), with a strong oxidizer, such as sodium bromate (NaBrO3) causes an exothermic reaction in the first stage, thereby removing the quartz layer and polymer coat in the filter cake by the in-situ generated HF acid. During the second stage for the barite-based filter cake, chelating agents combined with convertor catalysts were used to dissolve the barite. Solubility experiments were conducted to evaluate the efficiency at each stage in the filter cake removal process at 300 ºF and 500 psi. The experimental results showed that the formulation consisting of ammonium fluoride (NH4F), with a strong oxidizer (sodium bromate,NaBrO3), combined with exothermic reaction was able to generate HF in-situ, which in turn dissolved the quartz mineral and remove the polymer from the filter cake.Badr S. BageriIbrahim GomaaMohamed MahmoudShirish PatilAyman Al-NakhliNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 10, Iss 1, Pp 1-8 (2020) |
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Medicine R Science Q Badr S. Bageri Ibrahim Gomaa Mohamed Mahmoud Shirish Patil Ayman Al-Nakhli Complex barite filter cake removal using in-situ generated acids by thermochemicals |
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Abstract In sandstone formations, the quartz particles integrate with drilling fluid solids and become part of the filter cake structure. As a result, the dissolution rate of the filter cake diminishes and reduces the removal efficiency. This paper presents a novel solution to overcome the challenges that restricts the filter cake removal process such as the presence of the quartz layer and the polymer coat. A multi-stage method for removing the filter cake from a wellbore is presented. The composition of the new formulation is; ammonium fluoride (NH4F), with a strong oxidizer, such as sodium bromate (NaBrO3) causes an exothermic reaction in the first stage, thereby removing the quartz layer and polymer coat in the filter cake by the in-situ generated HF acid. During the second stage for the barite-based filter cake, chelating agents combined with convertor catalysts were used to dissolve the barite. Solubility experiments were conducted to evaluate the efficiency at each stage in the filter cake removal process at 300 ºF and 500 psi. The experimental results showed that the formulation consisting of ammonium fluoride (NH4F), with a strong oxidizer (sodium bromate,NaBrO3), combined with exothermic reaction was able to generate HF in-situ, which in turn dissolved the quartz mineral and remove the polymer from the filter cake. |
format |
article |
author |
Badr S. Bageri Ibrahim Gomaa Mohamed Mahmoud Shirish Patil Ayman Al-Nakhli |
author_facet |
Badr S. Bageri Ibrahim Gomaa Mohamed Mahmoud Shirish Patil Ayman Al-Nakhli |
author_sort |
Badr S. Bageri |
title |
Complex barite filter cake removal using in-situ generated acids by thermochemicals |
title_short |
Complex barite filter cake removal using in-situ generated acids by thermochemicals |
title_full |
Complex barite filter cake removal using in-situ generated acids by thermochemicals |
title_fullStr |
Complex barite filter cake removal using in-situ generated acids by thermochemicals |
title_full_unstemmed |
Complex barite filter cake removal using in-situ generated acids by thermochemicals |
title_sort |
complex barite filter cake removal using in-situ generated acids by thermochemicals |
publisher |
Nature Portfolio |
publishDate |
2020 |
url |
https://doaj.org/article/5e6f2903f0fe4802896c35fb2d98dee5 |
work_keys_str_mv |
AT badrsbageri complexbaritefiltercakeremovalusinginsitugeneratedacidsbythermochemicals AT ibrahimgomaa complexbaritefiltercakeremovalusinginsitugeneratedacidsbythermochemicals AT mohamedmahmoud complexbaritefiltercakeremovalusinginsitugeneratedacidsbythermochemicals AT shirishpatil complexbaritefiltercakeremovalusinginsitugeneratedacidsbythermochemicals AT aymanalnakhli complexbaritefiltercakeremovalusinginsitugeneratedacidsbythermochemicals |
_version_ |
1718377624786436096 |