Hydrogen Absorption and Desorption Behavior on Aluminum-Coated Hot-Stamped Boron Steel during Hot Press Forming and Automotive Manufacturing Processes

Our study mainly focused on diffusible hydrogen in aluminum–silicon-coated hot-stamped boron steel during a hot press forming process and in pre-treatment sequential lines of the automotive manufacturing process using a thermal desorption spectroscopy (TDS) technique. First, in the hot stamping proc...

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Autores principales: Hye-Jin Kim, Hyun-Yeong Jung, Seung-Pill Jung, Ji-Hee Son, Joo-Sik Hyun, Ju-Sung Kim
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:5f61adae51004471b7ba4d68037dec2d2021-11-11T18:13:11ZHydrogen Absorption and Desorption Behavior on Aluminum-Coated Hot-Stamped Boron Steel during Hot Press Forming and Automotive Manufacturing Processes10.3390/ma142167301996-1944https://doaj.org/article/5f61adae51004471b7ba4d68037dec2d2021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/21/6730https://doaj.org/toc/1996-1944Our study mainly focused on diffusible hydrogen in aluminum–silicon-coated hot-stamped boron steel during a hot press forming process and in pre-treatment sequential lines of the automotive manufacturing process using a thermal desorption spectroscopy (TDS) technique. First, in the hot stamping procedure, as the soaking time increased in the heating furnace at a specific dew point when austenitizing, a high concentration of diffusible hydrogen was absorbed into the hot-stamped boron steel. Based on the TDS analysis of hydrogen absorbed from hot stamping, the activation energy value of hydrogen trapping in 1.8 GPa grade steel is lower than that of 1.5 GPa grade steel. This means that diffusible hydrogen can be more easily diffused into defective sites of the microstructure at a higher level of the tensile strength grade. Second, in sequential pre-treatment lines of the automotive manufacturing process, additional hydrogen did not flow into the surface, and an electro-deposition process, including a baking procedure, was effective in removing diffusible hydrogen, which was similar to the residual hydrogen of the as-received state (i.e., initial cold rolled blank). Based on these results, the hydrogen absorption was facilitated during hot press forming, but the hydrogen was sequentially desorbed during automotive sequential lines on aluminum-coated hot-stamped steel parts.Hye-Jin KimHyun-Yeong JungSeung-Pill JungJi-Hee SonJoo-Sik HyunJu-Sung KimMDPI AGarticlehot-stamped boron steelthermal desorption spectroscopydiffusible hydrogenTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 6730, p 6730 (2021)
institution DOAJ
collection DOAJ
language EN
topic hot-stamped boron steel
thermal desorption spectroscopy
diffusible hydrogen
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
spellingShingle hot-stamped boron steel
thermal desorption spectroscopy
diffusible hydrogen
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
Hye-Jin Kim
Hyun-Yeong Jung
Seung-Pill Jung
Ji-Hee Son
Joo-Sik Hyun
Ju-Sung Kim
Hydrogen Absorption and Desorption Behavior on Aluminum-Coated Hot-Stamped Boron Steel during Hot Press Forming and Automotive Manufacturing Processes
description Our study mainly focused on diffusible hydrogen in aluminum–silicon-coated hot-stamped boron steel during a hot press forming process and in pre-treatment sequential lines of the automotive manufacturing process using a thermal desorption spectroscopy (TDS) technique. First, in the hot stamping procedure, as the soaking time increased in the heating furnace at a specific dew point when austenitizing, a high concentration of diffusible hydrogen was absorbed into the hot-stamped boron steel. Based on the TDS analysis of hydrogen absorbed from hot stamping, the activation energy value of hydrogen trapping in 1.8 GPa grade steel is lower than that of 1.5 GPa grade steel. This means that diffusible hydrogen can be more easily diffused into defective sites of the microstructure at a higher level of the tensile strength grade. Second, in sequential pre-treatment lines of the automotive manufacturing process, additional hydrogen did not flow into the surface, and an electro-deposition process, including a baking procedure, was effective in removing diffusible hydrogen, which was similar to the residual hydrogen of the as-received state (i.e., initial cold rolled blank). Based on these results, the hydrogen absorption was facilitated during hot press forming, but the hydrogen was sequentially desorbed during automotive sequential lines on aluminum-coated hot-stamped steel parts.
format article
author Hye-Jin Kim
Hyun-Yeong Jung
Seung-Pill Jung
Ji-Hee Son
Joo-Sik Hyun
Ju-Sung Kim
author_facet Hye-Jin Kim
Hyun-Yeong Jung
Seung-Pill Jung
Ji-Hee Son
Joo-Sik Hyun
Ju-Sung Kim
author_sort Hye-Jin Kim
title Hydrogen Absorption and Desorption Behavior on Aluminum-Coated Hot-Stamped Boron Steel during Hot Press Forming and Automotive Manufacturing Processes
title_short Hydrogen Absorption and Desorption Behavior on Aluminum-Coated Hot-Stamped Boron Steel during Hot Press Forming and Automotive Manufacturing Processes
title_full Hydrogen Absorption and Desorption Behavior on Aluminum-Coated Hot-Stamped Boron Steel during Hot Press Forming and Automotive Manufacturing Processes
title_fullStr Hydrogen Absorption and Desorption Behavior on Aluminum-Coated Hot-Stamped Boron Steel during Hot Press Forming and Automotive Manufacturing Processes
title_full_unstemmed Hydrogen Absorption and Desorption Behavior on Aluminum-Coated Hot-Stamped Boron Steel during Hot Press Forming and Automotive Manufacturing Processes
title_sort hydrogen absorption and desorption behavior on aluminum-coated hot-stamped boron steel during hot press forming and automotive manufacturing processes
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/5f61adae51004471b7ba4d68037dec2d
work_keys_str_mv AT hyejinkim hydrogenabsorptionanddesorptionbehavioronaluminumcoatedhotstampedboronsteelduringhotpressformingandautomotivemanufacturingprocesses
AT hyunyeongjung hydrogenabsorptionanddesorptionbehavioronaluminumcoatedhotstampedboronsteelduringhotpressformingandautomotivemanufacturingprocesses
AT seungpilljung hydrogenabsorptionanddesorptionbehavioronaluminumcoatedhotstampedboronsteelduringhotpressformingandautomotivemanufacturingprocesses
AT jiheeson hydrogenabsorptionanddesorptionbehavioronaluminumcoatedhotstampedboronsteelduringhotpressformingandautomotivemanufacturingprocesses
AT joosikhyun hydrogenabsorptionanddesorptionbehavioronaluminumcoatedhotstampedboronsteelduringhotpressformingandautomotivemanufacturingprocesses
AT jusungkim hydrogenabsorptionanddesorptionbehavioronaluminumcoatedhotstampedboronsteelduringhotpressformingandautomotivemanufacturingprocesses
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