Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal
Designing materials with large thermal expansion is highly desirable to fabricate microscale devices. The authors report unusually large anisotropic negative and positive thermal expansion in a simple crystalline material, through temperature-driven orientation of imidazole cations acting as molecul...
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2019
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oai:doaj.org-article:5fab38f7eaf5474b9d499adc1b2b53662021-12-02T17:01:34ZGiant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal10.1038/s41467-019-12833-y2041-1723https://doaj.org/article/5fab38f7eaf5474b9d499adc1b2b53662019-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12833-yhttps://doaj.org/toc/2041-1723Designing materials with large thermal expansion is highly desirable to fabricate microscale devices. The authors report unusually large anisotropic negative and positive thermal expansion in a simple crystalline material, through temperature-driven orientation of imidazole cations acting as molecular wheels.Zi-Shuo YaoHanxi GuanYoshihito ShiotaChun-Ting HeXiao-Lei WangShu-Qi WuXiaoyan ZhengSheng-Qun SuKazunari YoshizawaXueqian KongOsamu SatoJun TaoNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019) |
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Science Q |
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Science Q Zi-Shuo Yao Hanxi Guan Yoshihito Shiota Chun-Ting He Xiao-Lei Wang Shu-Qi Wu Xiaoyan Zheng Sheng-Qun Su Kazunari Yoshizawa Xueqian Kong Osamu Sato Jun Tao Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal |
description |
Designing materials with large thermal expansion is highly desirable to fabricate microscale devices. The authors report unusually large anisotropic negative and positive thermal expansion in a simple crystalline material, through temperature-driven orientation of imidazole cations acting as molecular wheels. |
format |
article |
author |
Zi-Shuo Yao Hanxi Guan Yoshihito Shiota Chun-Ting He Xiao-Lei Wang Shu-Qi Wu Xiaoyan Zheng Sheng-Qun Su Kazunari Yoshizawa Xueqian Kong Osamu Sato Jun Tao |
author_facet |
Zi-Shuo Yao Hanxi Guan Yoshihito Shiota Chun-Ting He Xiao-Lei Wang Shu-Qi Wu Xiaoyan Zheng Sheng-Qun Su Kazunari Yoshizawa Xueqian Kong Osamu Sato Jun Tao |
author_sort |
Zi-Shuo Yao |
title |
Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal |
title_short |
Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal |
title_full |
Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal |
title_fullStr |
Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal |
title_full_unstemmed |
Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal |
title_sort |
giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/5fab38f7eaf5474b9d499adc1b2b5366 |
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