Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal

Designing materials with large thermal expansion is highly desirable to fabricate microscale devices. The authors report unusually large anisotropic negative and positive thermal expansion in a simple crystalline material, through temperature-driven orientation of imidazole cations acting as molecul...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Zi-Shuo Yao, Hanxi Guan, Yoshihito Shiota, Chun-Ting He, Xiao-Lei Wang, Shu-Qi Wu, Xiaoyan Zheng, Sheng-Qun Su, Kazunari Yoshizawa, Xueqian Kong, Osamu Sato, Jun Tao
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
Materias:
Q
Acceso en línea:https://doaj.org/article/5fab38f7eaf5474b9d499adc1b2b5366
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:5fab38f7eaf5474b9d499adc1b2b5366
record_format dspace
spelling oai:doaj.org-article:5fab38f7eaf5474b9d499adc1b2b53662021-12-02T17:01:34ZGiant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal10.1038/s41467-019-12833-y2041-1723https://doaj.org/article/5fab38f7eaf5474b9d499adc1b2b53662019-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12833-yhttps://doaj.org/toc/2041-1723Designing materials with large thermal expansion is highly desirable to fabricate microscale devices. The authors report unusually large anisotropic negative and positive thermal expansion in a simple crystalline material, through temperature-driven orientation of imidazole cations acting as molecular wheels.Zi-Shuo YaoHanxi GuanYoshihito ShiotaChun-Ting HeXiao-Lei WangShu-Qi WuXiaoyan ZhengSheng-Qun SuKazunari YoshizawaXueqian KongOsamu SatoJun TaoNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Zi-Shuo Yao
Hanxi Guan
Yoshihito Shiota
Chun-Ting He
Xiao-Lei Wang
Shu-Qi Wu
Xiaoyan Zheng
Sheng-Qun Su
Kazunari Yoshizawa
Xueqian Kong
Osamu Sato
Jun Tao
Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal
description Designing materials with large thermal expansion is highly desirable to fabricate microscale devices. The authors report unusually large anisotropic negative and positive thermal expansion in a simple crystalline material, through temperature-driven orientation of imidazole cations acting as molecular wheels.
format article
author Zi-Shuo Yao
Hanxi Guan
Yoshihito Shiota
Chun-Ting He
Xiao-Lei Wang
Shu-Qi Wu
Xiaoyan Zheng
Sheng-Qun Su
Kazunari Yoshizawa
Xueqian Kong
Osamu Sato
Jun Tao
author_facet Zi-Shuo Yao
Hanxi Guan
Yoshihito Shiota
Chun-Ting He
Xiao-Lei Wang
Shu-Qi Wu
Xiaoyan Zheng
Sheng-Qun Su
Kazunari Yoshizawa
Xueqian Kong
Osamu Sato
Jun Tao
author_sort Zi-Shuo Yao
title Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal
title_short Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal
title_full Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal
title_fullStr Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal
title_full_unstemmed Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal
title_sort giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/5fab38f7eaf5474b9d499adc1b2b5366
work_keys_str_mv AT zishuoyao giantanisotropicthermalexpansionactuatedbythermodynamicallyassistedreorientationofimidazoliumsinasinglecrystal
AT hanxiguan giantanisotropicthermalexpansionactuatedbythermodynamicallyassistedreorientationofimidazoliumsinasinglecrystal
AT yoshihitoshiota giantanisotropicthermalexpansionactuatedbythermodynamicallyassistedreorientationofimidazoliumsinasinglecrystal
AT chuntinghe giantanisotropicthermalexpansionactuatedbythermodynamicallyassistedreorientationofimidazoliumsinasinglecrystal
AT xiaoleiwang giantanisotropicthermalexpansionactuatedbythermodynamicallyassistedreorientationofimidazoliumsinasinglecrystal
AT shuqiwu giantanisotropicthermalexpansionactuatedbythermodynamicallyassistedreorientationofimidazoliumsinasinglecrystal
AT xiaoyanzheng giantanisotropicthermalexpansionactuatedbythermodynamicallyassistedreorientationofimidazoliumsinasinglecrystal
AT shengqunsu giantanisotropicthermalexpansionactuatedbythermodynamicallyassistedreorientationofimidazoliumsinasinglecrystal
AT kazunariyoshizawa giantanisotropicthermalexpansionactuatedbythermodynamicallyassistedreorientationofimidazoliumsinasinglecrystal
AT xueqiankong giantanisotropicthermalexpansionactuatedbythermodynamicallyassistedreorientationofimidazoliumsinasinglecrystal
AT osamusato giantanisotropicthermalexpansionactuatedbythermodynamicallyassistedreorientationofimidazoliumsinasinglecrystal
AT juntao giantanisotropicthermalexpansionactuatedbythermodynamicallyassistedreorientationofimidazoliumsinasinglecrystal
_version_ 1718382085359534080