A Computational Procedure in Detecting Adulterated Oleochemical Products

Vegetable oils can be used as feedstock for the production of a large class of oleochemical products. Unfortunately, price disparities among different kinds of vegetables oils provide an incentive for adulteration by using cheaper substitutes while still claiming otherwise. In this paper, a chemical...

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Autores principales: Gian Paolo O. Bernardo, Michael Angelo B. Promentilla
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Lenguaje:EN
Publicado: AIDIC Servizi S.r.l. 2021
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Acceso en línea:https://doaj.org/article/5fbb2f804e614e8893c2f2645f62fc00
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spelling oai:doaj.org-article:5fbb2f804e614e8893c2f2645f62fc002021-11-15T21:47:40ZA Computational Procedure in Detecting Adulterated Oleochemical Products10.3303/CET21881352283-9216https://doaj.org/article/5fbb2f804e614e8893c2f2645f62fc002021-11-01T00:00:00Zhttps://www.cetjournal.it/index.php/cet/article/view/11928https://doaj.org/toc/2283-9216Vegetable oils can be used as feedstock for the production of a large class of oleochemical products. Unfortunately, price disparities among different kinds of vegetables oils provide an incentive for adulteration by using cheaper substitutes while still claiming otherwise. In this paper, a chemical forensics method for detecting whether or not such an adulteration has been committed is proposed and demonstrated in two case studies, each involving a batch of soap products supposedly produced using 100 % coconut oil and from 75 % coconut oil with 25 % palm oil. The concentration profiles of the fatty acids from soap samples were cross-referenced against known fatty acid concentration fingerprints for coconut oil and for palm oil from the Lipid Handbook through a linear programming model. Executing the model on the sample concentration profiles yielded the back-calculated concentrations of coconut oil and of palm oil used as feedstock with excellent agreement in both cases. The confirmation exhibited in these hypothetical case studies indicates that the procedure can be used in detecting adulteration in other oleochemical products of similar nature, and that the model can be used as a basis in the development of other adulteration detection methods.Gian Paolo O. BernardoMichael Angelo B. PromentillaAIDIC Servizi S.r.l.articleChemical engineeringTP155-156Computer engineering. Computer hardwareTK7885-7895ENChemical Engineering Transactions, Vol 88 (2021)
institution DOAJ
collection DOAJ
language EN
topic Chemical engineering
TP155-156
Computer engineering. Computer hardware
TK7885-7895
spellingShingle Chemical engineering
TP155-156
Computer engineering. Computer hardware
TK7885-7895
Gian Paolo O. Bernardo
Michael Angelo B. Promentilla
A Computational Procedure in Detecting Adulterated Oleochemical Products
description Vegetable oils can be used as feedstock for the production of a large class of oleochemical products. Unfortunately, price disparities among different kinds of vegetables oils provide an incentive for adulteration by using cheaper substitutes while still claiming otherwise. In this paper, a chemical forensics method for detecting whether or not such an adulteration has been committed is proposed and demonstrated in two case studies, each involving a batch of soap products supposedly produced using 100 % coconut oil and from 75 % coconut oil with 25 % palm oil. The concentration profiles of the fatty acids from soap samples were cross-referenced against known fatty acid concentration fingerprints for coconut oil and for palm oil from the Lipid Handbook through a linear programming model. Executing the model on the sample concentration profiles yielded the back-calculated concentrations of coconut oil and of palm oil used as feedstock with excellent agreement in both cases. The confirmation exhibited in these hypothetical case studies indicates that the procedure can be used in detecting adulteration in other oleochemical products of similar nature, and that the model can be used as a basis in the development of other adulteration detection methods.
format article
author Gian Paolo O. Bernardo
Michael Angelo B. Promentilla
author_facet Gian Paolo O. Bernardo
Michael Angelo B. Promentilla
author_sort Gian Paolo O. Bernardo
title A Computational Procedure in Detecting Adulterated Oleochemical Products
title_short A Computational Procedure in Detecting Adulterated Oleochemical Products
title_full A Computational Procedure in Detecting Adulterated Oleochemical Products
title_fullStr A Computational Procedure in Detecting Adulterated Oleochemical Products
title_full_unstemmed A Computational Procedure in Detecting Adulterated Oleochemical Products
title_sort computational procedure in detecting adulterated oleochemical products
publisher AIDIC Servizi S.r.l.
publishDate 2021
url https://doaj.org/article/5fbb2f804e614e8893c2f2645f62fc00
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