Controlled radical fluorination of poly(meth)acrylic acids in aqueous solution

Fluorinated alkenes have very poor reactivity in copolymerizations with non-fluorinated polar monomers. Here the authors show silver-catalyzed decarboxylative radical fluorination of poly(acrylic acid) with Selectfluor in water at room temperature to form poly(vinyl fluoride-co-acrylic acid) copolym...

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Autores principales:	Yucheng Dong, Zhentao Wang, Chaozhong Li
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/5fe02badc12c49bfa618f16ec8b3c5a6
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spelling	oai:doaj.org-article:5fe02badc12c49bfa618f16ec8b3c5a62021-12-02T13:24:05ZControlled radical fluorination of poly(meth)acrylic acids in aqueous solution10.1038/s41467-017-00376-z2041-1723https://doaj.org/article/5fe02badc12c49bfa618f16ec8b3c5a62017-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00376-zhttps://doaj.org/toc/2041-1723Fluorinated alkenes have very poor reactivity in copolymerizations with non-fluorinated polar monomers. Here the authors show silver-catalyzed decarboxylative radical fluorination of poly(acrylic acid) with Selectfluor in water at room temperature to form poly(vinyl fluoride-co-acrylic acid) copolymers.Yucheng DongZhentao WangChaozhong LiNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-5 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yucheng Dong Zhentao Wang Chaozhong Li Controlled radical fluorination of poly(meth)acrylic acids in aqueous solution
description	Fluorinated alkenes have very poor reactivity in copolymerizations with non-fluorinated polar monomers. Here the authors show silver-catalyzed decarboxylative radical fluorination of poly(acrylic acid) with Selectfluor in water at room temperature to form poly(vinyl fluoride-co-acrylic acid) copolymers.
format	article
author	Yucheng Dong Zhentao Wang Chaozhong Li
author_facet	Yucheng Dong Zhentao Wang Chaozhong Li
author_sort	Yucheng Dong
title	Controlled radical fluorination of poly(meth)acrylic acids in aqueous solution
title_short	Controlled radical fluorination of poly(meth)acrylic acids in aqueous solution
title_full	Controlled radical fluorination of poly(meth)acrylic acids in aqueous solution
title_fullStr	Controlled radical fluorination of poly(meth)acrylic acids in aqueous solution
title_full_unstemmed	Controlled radical fluorination of poly(meth)acrylic acids in aqueous solution
title_sort	controlled radical fluorination of poly(meth)acrylic acids in aqueous solution
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/5fe02badc12c49bfa618f16ec8b3c5a6
work_keys_str_mv	AT yuchengdong controlledradicalfluorinationofpolymethacrylicacidsinaqueoussolution AT zhentaowang controlledradicalfluorinationofpolymethacrylicacidsinaqueoussolution AT chaozhongli controlledradicalfluorinationofpolymethacrylicacidsinaqueoussolution
_version_	1718393153063485440

Controlled radical fluorination of poly(meth)acrylic acids in aqueous solution

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