Thermodynamic and Transport Properties of Biomass-Derived Furfural, Furfuryl Alcohol and Their Mixtures

The limited reserves and well-known disadvantages of using fossil energy sources have increased the need for appropriate renewable substitutes in the production of various chemicals and materials. Biomass has been shown to be worthy of attention since it can be converted to biofuels and value-added...

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Autores principales:	Zoran V. Simić, Mirjana Lj. Kijevčanin, Ivona R. Radović, Miha Grilc, Gorica R. Ivaniš
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	density speed of sound viscosity refractive index modelling binary mixtures Technology T
Acceso en línea:	https://doaj.org/article/607fe382b85646e2972c4a24f942d2eb
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spelling	oai:doaj.org-article:607fe382b85646e2972c4a24f942d2eb2021-11-25T17:28:37ZThermodynamic and Transport Properties of Biomass-Derived Furfural, Furfuryl Alcohol and Their Mixtures10.3390/en142277691996-1073https://doaj.org/article/607fe382b85646e2972c4a24f942d2eb2021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1073/14/22/7769https://doaj.org/toc/1996-1073The limited reserves and well-known disadvantages of using fossil energy sources have increased the need for appropriate renewable substitutes in the production of various chemicals and materials. Biomass has been shown to be worthy of attention since it can be converted to biofuels and value-added chemicals relatively easily. The design of biomass valorisation process requires knowledge on the thermodynamic behaviour of the biomass-derived compounds, such as furfural and furfuryl alcohol. The thermodynamic and transport properties of the binary system furfural + furfuryl alcohol were studied at various temperatures and pressures. Density, speed of sound and refractive index were measured in the temperature range <i>T =</i> (288.15–345.15) K and viscosity was measured at temperatures up to 373.15 K, all at atmospheric pressure. Further, the density of pure components was obtained in the temperature range (293.15–413.15) K for furfural and (293.15–373.15) K for furfuryl alcohol at pressures up to 60.0 MPa. The obtained density values were correlated using the modified Tammann–Tait equation with an average absolute deviation lower than 0.009% for furfural and furfuryl alcohol. The optimised parameters were used for the calculation of the isothermal compressibility, the isobaric thermal expansivity, the internal pressure and the isobaric and isochoric specific heat capacities. The reported data are a valuable source of information for the further application of the investigated compounds.Zoran V. SimićMirjana Lj. KijevčaninIvona R. RadovićMiha GrilcGorica R. IvanišMDPI AGarticledensityspeed of soundviscosityrefractive indexmodellingbinary mixturesTechnologyTENEnergies, Vol 14, Iss 7769, p 7769 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	density speed of sound viscosity refractive index modelling binary mixtures Technology T
spellingShingle	density speed of sound viscosity refractive index modelling binary mixtures Technology T Zoran V. Simić Mirjana Lj. Kijevčanin Ivona R. Radović Miha Grilc Gorica R. Ivaniš Thermodynamic and Transport Properties of Biomass-Derived Furfural, Furfuryl Alcohol and Their Mixtures
description	The limited reserves and well-known disadvantages of using fossil energy sources have increased the need for appropriate renewable substitutes in the production of various chemicals and materials. Biomass has been shown to be worthy of attention since it can be converted to biofuels and value-added chemicals relatively easily. The design of biomass valorisation process requires knowledge on the thermodynamic behaviour of the biomass-derived compounds, such as furfural and furfuryl alcohol. The thermodynamic and transport properties of the binary system furfural + furfuryl alcohol were studied at various temperatures and pressures. Density, speed of sound and refractive index were measured in the temperature range <i>T =</i> (288.15–345.15) K and viscosity was measured at temperatures up to 373.15 K, all at atmospheric pressure. Further, the density of pure components was obtained in the temperature range (293.15–413.15) K for furfural and (293.15–373.15) K for furfuryl alcohol at pressures up to 60.0 MPa. The obtained density values were correlated using the modified Tammann–Tait equation with an average absolute deviation lower than 0.009% for furfural and furfuryl alcohol. The optimised parameters were used for the calculation of the isothermal compressibility, the isobaric thermal expansivity, the internal pressure and the isobaric and isochoric specific heat capacities. The reported data are a valuable source of information for the further application of the investigated compounds.
format	article
author	Zoran V. Simić Mirjana Lj. Kijevčanin Ivona R. Radović Miha Grilc Gorica R. Ivaniš
author_facet	Zoran V. Simić Mirjana Lj. Kijevčanin Ivona R. Radović Miha Grilc Gorica R. Ivaniš
author_sort	Zoran V. Simić
title	Thermodynamic and Transport Properties of Biomass-Derived Furfural, Furfuryl Alcohol and Their Mixtures
title_short	Thermodynamic and Transport Properties of Biomass-Derived Furfural, Furfuryl Alcohol and Their Mixtures
title_full	Thermodynamic and Transport Properties of Biomass-Derived Furfural, Furfuryl Alcohol and Their Mixtures
title_fullStr	Thermodynamic and Transport Properties of Biomass-Derived Furfural, Furfuryl Alcohol and Their Mixtures
title_full_unstemmed	Thermodynamic and Transport Properties of Biomass-Derived Furfural, Furfuryl Alcohol and Their Mixtures
title_sort	thermodynamic and transport properties of biomass-derived furfural, furfuryl alcohol and their mixtures
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/607fe382b85646e2972c4a24f942d2eb
work_keys_str_mv	AT zoranvsimic thermodynamicandtransportpropertiesofbiomassderivedfurfuralfurfurylalcoholandtheirmixtures AT mirjanaljkijevcanin thermodynamicandtransportpropertiesofbiomassderivedfurfuralfurfurylalcoholandtheirmixtures AT ivonarradovic thermodynamicandtransportpropertiesofbiomassderivedfurfuralfurfurylalcoholandtheirmixtures AT mihagrilc thermodynamicandtransportpropertiesofbiomassderivedfurfuralfurfurylalcoholandtheirmixtures AT goricarivanis thermodynamicandtransportpropertiesofbiomassderivedfurfuralfurfurylalcoholandtheirmixtures
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Thermodynamic and Transport Properties of Biomass-Derived Furfural, Furfuryl Alcohol and Their Mixtures

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