Progress and perspective of Li1 + xAlxTi2‐x(PO4)3 ceramic electrolyte in lithium batteries

Abstract The replacement of liquid organic electrolytes with solid‐state electrolytes (SSEs) is a feasible way to solve the safety issues and improve the energy density of lithium batteries. Developing SSEs materials that can well match with high‐voltage cathodes and lithium metal anode is quite sig...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Ke Yang, Likun Chen, Jiabin Ma, Yan‐Bing He, Feiyu Kang
Formato:	article
Lenguaje:	EN
Publicado:	Wiley 2021
Materias:	crystal structure interfaces ionic conductivity Li1 + xAlxTi2 ‐ x(PO4)3 lithium batteries Materials of engineering and construction. Mechanics of materials TA401-492 Information technology T58.5-58.64
Acceso en línea:	https://doaj.org/article/60a0a8185a1f43229171014c2a8f83c8
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:60a0a8185a1f43229171014c2a8f83c8
record_format	dspace
spelling	oai:doaj.org-article:60a0a8185a1f43229171014c2a8f83c82021-11-16T06:26:52ZProgress and perspective of Li1 + xAlxTi2‐x(PO4)3 ceramic electrolyte in lithium batteries2567-316510.1002/inf2.12222https://doaj.org/article/60a0a8185a1f43229171014c2a8f83c82021-11-01T00:00:00Zhttps://doi.org/10.1002/inf2.12222https://doaj.org/toc/2567-3165Abstract The replacement of liquid organic electrolytes with solid‐state electrolytes (SSEs) is a feasible way to solve the safety issues and improve the energy density of lithium batteries. Developing SSEs materials that can well match with high‐voltage cathodes and lithium metal anode is quite significant to develop high‐energy‐density lithium batteries. Li1 + xAlxTi2 ‐ x(PO4)3 (LATP) SSE with NASICON structure exhibits high ionic conductivity, low cost and superior air stability, which enable it as one of the most hopeful candidates for all‐solid‐state batteries (ASSBs). However, the high interfacial impedance between LATP and electrodes, and the severe interfacial side reactions with the lithium metal greatly limit its applications in ASSBs. This review introduces the crystal structure and ion transport mechanisms of LATP and summarizes the key factors affecting the ionic conductivity. The side reaction mechanisms of LATP with Li metal and the promising strategies for optimizing interfacial compatibility are reviewed. We also summarize the applications of LATP including as surface coatings of cathode particles, ion transport network additives and inorganic fillers of composite polymer electrolytes. At last, this review proposes the challenges and the future development directions of LATP in SSBs.Ke YangLikun ChenJiabin MaYan‐Bing HeFeiyu KangWileyarticlecrystal structureinterfacesionic conductivityLi1 + xAlxTi2 ‐ x(PO4)3lithium batteriesMaterials of engineering and construction. Mechanics of materialsTA401-492Information technologyT58.5-58.64ENInfoMat, Vol 3, Iss 11, Pp 1195-1217 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	crystal structure interfaces ionic conductivity Li1 + xAlxTi2 ‐ x(PO4)3 lithium batteries Materials of engineering and construction. Mechanics of materials TA401-492 Information technology T58.5-58.64
spellingShingle	crystal structure interfaces ionic conductivity Li1 + xAlxTi2 ‐ x(PO4)3 lithium batteries Materials of engineering and construction. Mechanics of materials TA401-492 Information technology T58.5-58.64 Ke Yang Likun Chen Jiabin Ma Yan‐Bing He Feiyu Kang Progress and perspective of Li1 + xAlxTi2‐x(PO4)3 ceramic electrolyte in lithium batteries
description	Abstract The replacement of liquid organic electrolytes with solid‐state electrolytes (SSEs) is a feasible way to solve the safety issues and improve the energy density of lithium batteries. Developing SSEs materials that can well match with high‐voltage cathodes and lithium metal anode is quite significant to develop high‐energy‐density lithium batteries. Li1 + xAlxTi2 ‐ x(PO4)3 (LATP) SSE with NASICON structure exhibits high ionic conductivity, low cost and superior air stability, which enable it as one of the most hopeful candidates for all‐solid‐state batteries (ASSBs). However, the high interfacial impedance between LATP and electrodes, and the severe interfacial side reactions with the lithium metal greatly limit its applications in ASSBs. This review introduces the crystal structure and ion transport mechanisms of LATP and summarizes the key factors affecting the ionic conductivity. The side reaction mechanisms of LATP with Li metal and the promising strategies for optimizing interfacial compatibility are reviewed. We also summarize the applications of LATP including as surface coatings of cathode particles, ion transport network additives and inorganic fillers of composite polymer electrolytes. At last, this review proposes the challenges and the future development directions of LATP in SSBs.
format	article
author	Ke Yang Likun Chen Jiabin Ma Yan‐Bing He Feiyu Kang
author_facet	Ke Yang Likun Chen Jiabin Ma Yan‐Bing He Feiyu Kang
author_sort	Ke Yang
title	Progress and perspective of Li1 + xAlxTi2‐x(PO4)3 ceramic electrolyte in lithium batteries
title_short	Progress and perspective of Li1 + xAlxTi2‐x(PO4)3 ceramic electrolyte in lithium batteries
title_full	Progress and perspective of Li1 + xAlxTi2‐x(PO4)3 ceramic electrolyte in lithium batteries
title_fullStr	Progress and perspective of Li1 + xAlxTi2‐x(PO4)3 ceramic electrolyte in lithium batteries
title_full_unstemmed	Progress and perspective of Li1 + xAlxTi2‐x(PO4)3 ceramic electrolyte in lithium batteries
title_sort	progress and perspective of li1 + xalxti2‐x(po4)3 ceramic electrolyte in lithium batteries
publisher	Wiley
publishDate	2021
url	https://doaj.org/article/60a0a8185a1f43229171014c2a8f83c8
work_keys_str_mv	AT keyang progressandperspectiveofli1xalxti2xpo43ceramicelectrolyteinlithiumbatteries AT likunchen progressandperspectiveofli1xalxti2xpo43ceramicelectrolyteinlithiumbatteries AT jiabinma progressandperspectiveofli1xalxti2xpo43ceramicelectrolyteinlithiumbatteries AT yanbinghe progressandperspectiveofli1xalxti2xpo43ceramicelectrolyteinlithiumbatteries AT feiyukang progressandperspectiveofli1xalxti2xpo43ceramicelectrolyteinlithiumbatteries
_version_	1718426667634917376

Progress and perspective of Li1 + xAlxTi2‐x(PO4)3 ceramic electrolyte in lithium batteries

Ejemplares similares