Chiroptical activity of hydroxycarboxylic acids with implications for the origin of biological homochirality

Enantiomerically-enriched hydroxycarboxylic acids have been found in meteorites, but the possible origin of this asymmetry has not been explored experimentally. Here circular dichroism/anisotropy experiments suggest a common astrochemical mechanism for the generation of enantiomeric excess in hydrox...

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Bibliographic Details
Main Authors: Jana Bocková, Nykola C. Jones, Uwe J. Meierhenrich, Søren V. Hoffmann, Cornelia Meinert
Format: article
Language:EN
Published: Nature Portfolio 2021
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Online Access:https://doaj.org/article/60c8a2728ee640f9807d0c57e4c9c398
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Summary:Enantiomerically-enriched hydroxycarboxylic acids have been found in meteorites, but the possible origin of this asymmetry has not been explored experimentally. Here circular dichroism/anisotropy experiments suggest a common astrochemical mechanism for the generation of enantiomeric excess in hydroxycarboxylic acids and amino acids.