Facile Synthesis of Cobalt Ferrite (CoFe<sub>2</sub>O<sub>4</sub>) Nanoparticles in the Presence of Sodium Bis (2-ethyl-hexyl) Sulfosuccinate and Their Application in Dyes Removal from Single and Binary Aqueous Solutions

A research study was conducted to establish the effect of the presence of sodium bis-2-ethyl-hexyl-sulfosuccinate (DOSS) surfactant on the size, shape, and magnetic properties of cobalt ferrite nanoparticles, and also on their ability to remove anionic dyes from synthetic aqueous solutions. The effe...

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Autores principales: Claudia Maria Simonescu, Alina Tătăruş, Daniela Cristina Culiţă, Nicolae Stănică, Bogdan Butoi, Andrei Kuncser
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:610299b19e7647e0b8bf8207b7e8233a2021-11-25T18:32:40ZFacile Synthesis of Cobalt Ferrite (CoFe<sub>2</sub>O<sub>4</sub>) Nanoparticles in the Presence of Sodium Bis (2-ethyl-hexyl) Sulfosuccinate and Their Application in Dyes Removal from Single and Binary Aqueous Solutions10.3390/nano111131282079-4991https://doaj.org/article/610299b19e7647e0b8bf8207b7e8233a2021-11-01T00:00:00Zhttps://www.mdpi.com/2079-4991/11/11/3128https://doaj.org/toc/2079-4991A research study was conducted to establish the effect of the presence of sodium bis-2-ethyl-hexyl-sulfosuccinate (DOSS) surfactant on the size, shape, and magnetic properties of cobalt ferrite nanoparticles, and also on their ability to remove anionic dyes from synthetic aqueous solutions. The effect of the molar ratio cobalt ferrite to surfactant (1:0.1; 1:0.25 and 1:0.5) on the physicochemical properties of the prepared cobalt ferrite particles was evaluated using different characterization techniques, such as FT-IR spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), N<sub>2</sub> adsorption-desorption analysis, and magnetic measurements. The results revealed that the surfactant has a significant impact on the textural and magnetic properties of CoFe<sub>2</sub>O<sub>4</sub>. The capacity of the synthesized CoFe<sub>2</sub>O<sub>4</sub> samples to remove two anionic dyes, Congo Red (CR) and Methyl Orange (MO), by adsorption from aqueous solutions and the factors affecting the adsorption process, such as contact time, concentration of dyes in the initial solution, pH of the media, and the presence of a competing agent were investigated in batch experiments. Desorption experiments were performed to demonstrate the reusability of the adsorbents.Claudia Maria SimonescuAlina TătăruşDaniela Cristina CuliţăNicolae StănicăBogdan ButoiAndrei KuncserMDPI AGarticleanionic dyes adsorptionCongo RedMethyl Orangemagnetic adsorbentssurfactant effectsChemistryQD1-999ENNanomaterials, Vol 11, Iss 3128, p 3128 (2021)
institution DOAJ
collection DOAJ
language EN
topic anionic dyes adsorption
Congo Red
Methyl Orange
magnetic adsorbents
surfactant effects
Chemistry
QD1-999
spellingShingle anionic dyes adsorption
Congo Red
Methyl Orange
magnetic adsorbents
surfactant effects
Chemistry
QD1-999
Claudia Maria Simonescu
Alina Tătăruş
Daniela Cristina Culiţă
Nicolae Stănică
Bogdan Butoi
Andrei Kuncser
Facile Synthesis of Cobalt Ferrite (CoFe<sub>2</sub>O<sub>4</sub>) Nanoparticles in the Presence of Sodium Bis (2-ethyl-hexyl) Sulfosuccinate and Their Application in Dyes Removal from Single and Binary Aqueous Solutions
description A research study was conducted to establish the effect of the presence of sodium bis-2-ethyl-hexyl-sulfosuccinate (DOSS) surfactant on the size, shape, and magnetic properties of cobalt ferrite nanoparticles, and also on their ability to remove anionic dyes from synthetic aqueous solutions. The effect of the molar ratio cobalt ferrite to surfactant (1:0.1; 1:0.25 and 1:0.5) on the physicochemical properties of the prepared cobalt ferrite particles was evaluated using different characterization techniques, such as FT-IR spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), N<sub>2</sub> adsorption-desorption analysis, and magnetic measurements. The results revealed that the surfactant has a significant impact on the textural and magnetic properties of CoFe<sub>2</sub>O<sub>4</sub>. The capacity of the synthesized CoFe<sub>2</sub>O<sub>4</sub> samples to remove two anionic dyes, Congo Red (CR) and Methyl Orange (MO), by adsorption from aqueous solutions and the factors affecting the adsorption process, such as contact time, concentration of dyes in the initial solution, pH of the media, and the presence of a competing agent were investigated in batch experiments. Desorption experiments were performed to demonstrate the reusability of the adsorbents.
format article
author Claudia Maria Simonescu
Alina Tătăruş
Daniela Cristina Culiţă
Nicolae Stănică
Bogdan Butoi
Andrei Kuncser
author_facet Claudia Maria Simonescu
Alina Tătăruş
Daniela Cristina Culiţă
Nicolae Stănică
Bogdan Butoi
Andrei Kuncser
author_sort Claudia Maria Simonescu
title Facile Synthesis of Cobalt Ferrite (CoFe<sub>2</sub>O<sub>4</sub>) Nanoparticles in the Presence of Sodium Bis (2-ethyl-hexyl) Sulfosuccinate and Their Application in Dyes Removal from Single and Binary Aqueous Solutions
title_short Facile Synthesis of Cobalt Ferrite (CoFe<sub>2</sub>O<sub>4</sub>) Nanoparticles in the Presence of Sodium Bis (2-ethyl-hexyl) Sulfosuccinate and Their Application in Dyes Removal from Single and Binary Aqueous Solutions
title_full Facile Synthesis of Cobalt Ferrite (CoFe<sub>2</sub>O<sub>4</sub>) Nanoparticles in the Presence of Sodium Bis (2-ethyl-hexyl) Sulfosuccinate and Their Application in Dyes Removal from Single and Binary Aqueous Solutions
title_fullStr Facile Synthesis of Cobalt Ferrite (CoFe<sub>2</sub>O<sub>4</sub>) Nanoparticles in the Presence of Sodium Bis (2-ethyl-hexyl) Sulfosuccinate and Their Application in Dyes Removal from Single and Binary Aqueous Solutions
title_full_unstemmed Facile Synthesis of Cobalt Ferrite (CoFe<sub>2</sub>O<sub>4</sub>) Nanoparticles in the Presence of Sodium Bis (2-ethyl-hexyl) Sulfosuccinate and Their Application in Dyes Removal from Single and Binary Aqueous Solutions
title_sort facile synthesis of cobalt ferrite (cofe<sub>2</sub>o<sub>4</sub>) nanoparticles in the presence of sodium bis (2-ethyl-hexyl) sulfosuccinate and their application in dyes removal from single and binary aqueous solutions
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/610299b19e7647e0b8bf8207b7e8233a
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