Pd(OAc)2-catalyzed asymmetric hydrogenation of sterically hindered N-tosylimines

Pd(OAc)2-catalyzed asymmetric hydrogenation of sterically hindered N-tosylimines

Sterically hindered unsaturated compounds are challenging substrates for asymmetric hydrogenation. Here, the authors report a palladium/chiral (bis)phosphine catalytic system that hydrogenates a number of hindered N-tosylimines with excellent enantioselectivitites.

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Autores principales: Jianzhong Chen, Zhenfeng Zhang, Bowen Li, Feilong Li, Yulin Wang, Min Zhao, Ilya D. Gridnev, Tsuneo Imamoto, Wanbin Zhang
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Science
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Acceso en línea:https://doaj.org/article/61887082b7564dc1b11a43ae2c800e82
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