Adsorption of reactive blue 49 onto cross-linked chitosan-based composites containing waste mussel shell and waste active sludge char

Cross-linked chitosan/waste mussel shell (C/WMS) and chitosan/waste mussel shell/waste active sludge char (C/WMS/WASC) composites were prepared from waste mussel shell, waste active sludge (WAS), and chitosan, and cross-linked with glutaraldehyde. The quantities of chitosan, WMS, and WASC used for t...

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Autores principales: Deniz Akin Sahbaz, Sahra Dandil, Caglayan Acikgoz
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Publicado: IWA Publishing 2021
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spelling oai:doaj.org-article:62b4d585b1a34ef18f10345d8aa6c5402021-11-06T10:42:44ZAdsorption of reactive blue 49 onto cross-linked chitosan-based composites containing waste mussel shell and waste active sludge char0273-12231996-973210.2166/wst.2021.008https://doaj.org/article/62b4d585b1a34ef18f10345d8aa6c5402021-02-01T00:00:00Zhttp://wst.iwaponline.com/content/83/3/715https://doaj.org/toc/0273-1223https://doaj.org/toc/1996-9732Cross-linked chitosan/waste mussel shell (C/WMS) and chitosan/waste mussel shell/waste active sludge char (C/WMS/WASC) composites were prepared from waste mussel shell, waste active sludge (WAS), and chitosan, and cross-linked with glutaraldehyde. The quantities of chitosan, WMS, and WASC used for the C/WMS and C/WMS/WASC composites were 1:1 and 1:0.5:0.5, respectively. The two adsorbents were characterized for their quality by a scanning electron microscope (SEM), an energy-dispersive X-ray spectroscopy (EDX), and a Brunauer, Emmett and Teller (BET) analyzer. The effects of contact time (0–1,620 mins), pH (1–5), adsorbent dosage (0.01–0.1 g/50 ml), initial dye concentration (20–100 mg/L), and temperature (25–45 °C) on Reactive Blue 49 (RB49) adsorption onto C/WMS and C/WMS/WASC composites were investigated. The maximum RB49 adsorption capacity of C/WMS and C/WMS/WASC composites was 54.7 and 38.8 mg/g, respectively. The experimental data were analyzed by kinetic and isotherm models. The Freundlich isotherm was a good fit for the experimental data of RB49 adsorption on C/WMS and C/WMS/WASC composites, and the adsorption kinetics for both adsorbents were the pseudo-second-order rate equation. All results showed the preparative adsorbents can be used as effective adsorbents for the treatment of waste water contaminated with RB49 since they are low cost and eco-friendly for the environment.Deniz Akin SahbazSahra DandilCaglayan AcikgozIWA Publishingarticlecompositedye removalisothermkineticthermodynamicsEnvironmental technology. Sanitary engineeringTD1-1066ENWater Science and Technology, Vol 83, Iss 3, Pp 715-726 (2021)
institution DOAJ
collection DOAJ
language EN
topic composite
dye removal
isotherm
kinetic
thermodynamics
Environmental technology. Sanitary engineering
TD1-1066
spellingShingle composite
dye removal
isotherm
kinetic
thermodynamics
Environmental technology. Sanitary engineering
TD1-1066
Deniz Akin Sahbaz
Sahra Dandil
Caglayan Acikgoz
Adsorption of reactive blue 49 onto cross-linked chitosan-based composites containing waste mussel shell and waste active sludge char
description Cross-linked chitosan/waste mussel shell (C/WMS) and chitosan/waste mussel shell/waste active sludge char (C/WMS/WASC) composites were prepared from waste mussel shell, waste active sludge (WAS), and chitosan, and cross-linked with glutaraldehyde. The quantities of chitosan, WMS, and WASC used for the C/WMS and C/WMS/WASC composites were 1:1 and 1:0.5:0.5, respectively. The two adsorbents were characterized for their quality by a scanning electron microscope (SEM), an energy-dispersive X-ray spectroscopy (EDX), and a Brunauer, Emmett and Teller (BET) analyzer. The effects of contact time (0–1,620 mins), pH (1–5), adsorbent dosage (0.01–0.1 g/50 ml), initial dye concentration (20–100 mg/L), and temperature (25–45 °C) on Reactive Blue 49 (RB49) adsorption onto C/WMS and C/WMS/WASC composites were investigated. The maximum RB49 adsorption capacity of C/WMS and C/WMS/WASC composites was 54.7 and 38.8 mg/g, respectively. The experimental data were analyzed by kinetic and isotherm models. The Freundlich isotherm was a good fit for the experimental data of RB49 adsorption on C/WMS and C/WMS/WASC composites, and the adsorption kinetics for both adsorbents were the pseudo-second-order rate equation. All results showed the preparative adsorbents can be used as effective adsorbents for the treatment of waste water contaminated with RB49 since they are low cost and eco-friendly for the environment.
format article
author Deniz Akin Sahbaz
Sahra Dandil
Caglayan Acikgoz
author_facet Deniz Akin Sahbaz
Sahra Dandil
Caglayan Acikgoz
author_sort Deniz Akin Sahbaz
title Adsorption of reactive blue 49 onto cross-linked chitosan-based composites containing waste mussel shell and waste active sludge char
title_short Adsorption of reactive blue 49 onto cross-linked chitosan-based composites containing waste mussel shell and waste active sludge char
title_full Adsorption of reactive blue 49 onto cross-linked chitosan-based composites containing waste mussel shell and waste active sludge char
title_fullStr Adsorption of reactive blue 49 onto cross-linked chitosan-based composites containing waste mussel shell and waste active sludge char
title_full_unstemmed Adsorption of reactive blue 49 onto cross-linked chitosan-based composites containing waste mussel shell and waste active sludge char
title_sort adsorption of reactive blue 49 onto cross-linked chitosan-based composites containing waste mussel shell and waste active sludge char
publisher IWA Publishing
publishDate 2021
url https://doaj.org/article/62b4d585b1a34ef18f10345d8aa6c540
work_keys_str_mv AT denizakinsahbaz adsorptionofreactiveblue49ontocrosslinkedchitosanbasedcompositescontainingwastemusselshellandwasteactivesludgechar
AT sahradandil adsorptionofreactiveblue49ontocrosslinkedchitosanbasedcompositescontainingwastemusselshellandwasteactivesludgechar
AT caglayanacikgoz adsorptionofreactiveblue49ontocrosslinkedchitosanbasedcompositescontainingwastemusselshellandwasteactivesludgechar
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