Effect of the 2D phonon spectrum on the electric conductivity and thermopower of tetrathiotetracene iodide crystals
Thermoelectric transport along the molecular chains of quasi-one-dimensional organic crystals of tetrathiotetracene iodide, TTT2I3, is studied in terms of a quasi-two dimensional (2D) model applying the linearized Boltzmann kinetic equation. Earlier, for simplicity, we have considered the lattice vi...
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D.Ghitu Institute of Electronic Engineering and Nanotechnologies
2014
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oai:doaj.org-article:63f68a71bdfa4fb7a1546a371f4df07f2021-11-21T11:58:49ZEffect of the 2D phonon spectrum on the electric conductivity and thermopower of tetrathiotetracene iodide crystals537.323+539+621.3822537-63651810-648Xhttps://doaj.org/article/63f68a71bdfa4fb7a1546a371f4df07f2014-12-01T00:00:00Zhttps://mjps.nanotech.md/archive/2014/article/39441https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365Thermoelectric transport along the molecular chains of quasi-one-dimensional organic crystals of tetrathiotetracene iodide, TTT2I3, is studied in terms of a quasi-two dimensional (2D) model applying the linearized Boltzmann kinetic equation. Earlier, for simplicity, we have considered the lattice vibrations in a 1D approximation. In this paper, the full 2D spectrum for acoustic longitudinal phonons is taken into account and the effect of this consideration on the electric conductivity and thermopower (Seebeck coefficient) is studied. Numerical results and comparison with previous calculations are presented. It is shown that, if the 2D phonon spectrum is taken instead of the 1D one, the electric conductivity slightly increases and the thermopower decreases, although insignificantlySanduleac, IonelD.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 13, Iss 3-4, Pp 138-143 (2014) |
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Physics QC1-999 Electronics TK7800-8360 |
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Physics QC1-999 Electronics TK7800-8360 Sanduleac, Ionel Effect of the 2D phonon spectrum on the electric conductivity and thermopower of tetrathiotetracene iodide crystals |
description |
Thermoelectric transport along the molecular chains of quasi-one-dimensional organic crystals of tetrathiotetracene iodide, TTT2I3, is studied in terms of a quasi-two dimensional (2D) model applying the linearized Boltzmann kinetic equation. Earlier, for simplicity, we have considered the lattice vibrations in a 1D approximation. In this paper, the full 2D spectrum for acoustic longitudinal phonons is taken into account and the effect of this consideration on the electric conductivity and thermopower (Seebeck coefficient) is studied. Numerical results and comparison with previous calculations are presented. It is shown that, if the 2D phonon spectrum is taken instead of the 1D one, the electric conductivity slightly increases and the thermopower decreases, although insignificantly |
format |
article |
author |
Sanduleac, Ionel |
author_facet |
Sanduleac, Ionel |
author_sort |
Sanduleac, Ionel |
title |
Effect of the 2D phonon spectrum on the electric conductivity and thermopower of tetrathiotetracene iodide crystals |
title_short |
Effect of the 2D phonon spectrum on the electric conductivity and thermopower of tetrathiotetracene iodide crystals |
title_full |
Effect of the 2D phonon spectrum on the electric conductivity and thermopower of tetrathiotetracene iodide crystals |
title_fullStr |
Effect of the 2D phonon spectrum on the electric conductivity and thermopower of tetrathiotetracene iodide crystals |
title_full_unstemmed |
Effect of the 2D phonon spectrum on the electric conductivity and thermopower of tetrathiotetracene iodide crystals |
title_sort |
effect of the 2d phonon spectrum on the electric conductivity and thermopower of tetrathiotetracene iodide crystals |
publisher |
D.Ghitu Institute of Electronic Engineering and Nanotechnologies |
publishDate |
2014 |
url |
https://doaj.org/article/63f68a71bdfa4fb7a1546a371f4df07f |
work_keys_str_mv |
AT sanduleacionel effectofthe2dphononspectrumontheelectricconductivityandthermopoweroftetrathiotetraceneiodidecrystals |
_version_ |
1718419308160221184 |