Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst

The direct substitution of the OH group of stereogenic alcohols are reported rarely in literature. Here, the authors demonstrate direct substitution of both secondary and tertiary alcohols with chirality transfer leading to enantioenriched 5-membered, 6-membered and aryl-fused 6-membered heterocycli...

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Autores principales: Rahul A. Watile, Anon Bunrit, Jèssica Margalef, Sunisa Akkarasamiyo, Rabia Ayub, Emi Lagerspets, Srijit Biswas, Timo Repo, Joseph S. M. Samec
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Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/642177931c6547d3ba77fdf91901c007
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spelling oai:doaj.org-article:642177931c6547d3ba77fdf91901c0072021-12-02T16:50:59ZIntramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst10.1038/s41467-019-11838-x2041-1723https://doaj.org/article/642177931c6547d3ba77fdf91901c0072019-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-11838-xhttps://doaj.org/toc/2041-1723The direct substitution of the OH group of stereogenic alcohols are reported rarely in literature. Here, the authors demonstrate direct substitution of both secondary and tertiary alcohols with chirality transfer leading to enantioenriched 5-membered, 6-membered and aryl-fused 6-membered heterocyclic compounds.Rahul A. WatileAnon BunritJèssica MargalefSunisa AkkarasamiyoRabia AyubEmi LagerspetsSrijit BiswasTimo RepoJoseph S. M. SamecNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Rahul A. Watile
Anon Bunrit
Jèssica Margalef
Sunisa Akkarasamiyo
Rabia Ayub
Emi Lagerspets
Srijit Biswas
Timo Repo
Joseph S. M. Samec
Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst
description The direct substitution of the OH group of stereogenic alcohols are reported rarely in literature. Here, the authors demonstrate direct substitution of both secondary and tertiary alcohols with chirality transfer leading to enantioenriched 5-membered, 6-membered and aryl-fused 6-membered heterocyclic compounds.
format article
author Rahul A. Watile
Anon Bunrit
Jèssica Margalef
Sunisa Akkarasamiyo
Rabia Ayub
Emi Lagerspets
Srijit Biswas
Timo Repo
Joseph S. M. Samec
author_facet Rahul A. Watile
Anon Bunrit
Jèssica Margalef
Sunisa Akkarasamiyo
Rabia Ayub
Emi Lagerspets
Srijit Biswas
Timo Repo
Joseph S. M. Samec
author_sort Rahul A. Watile
title Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst
title_short Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst
title_full Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst
title_fullStr Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst
title_full_unstemmed Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst
title_sort intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(iii) catalyst
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/642177931c6547d3ba77fdf91901c007
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