Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst
The direct substitution of the OH group of stereogenic alcohols are reported rarely in literature. Here, the authors demonstrate direct substitution of both secondary and tertiary alcohols with chirality transfer leading to enantioenriched 5-membered, 6-membered and aryl-fused 6-membered heterocycli...
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Nature Portfolio
2019
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oai:doaj.org-article:642177931c6547d3ba77fdf91901c0072021-12-02T16:50:59ZIntramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst10.1038/s41467-019-11838-x2041-1723https://doaj.org/article/642177931c6547d3ba77fdf91901c0072019-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-11838-xhttps://doaj.org/toc/2041-1723The direct substitution of the OH group of stereogenic alcohols are reported rarely in literature. Here, the authors demonstrate direct substitution of both secondary and tertiary alcohols with chirality transfer leading to enantioenriched 5-membered, 6-membered and aryl-fused 6-membered heterocyclic compounds.Rahul A. WatileAnon BunritJèssica MargalefSunisa AkkarasamiyoRabia AyubEmi LagerspetsSrijit BiswasTimo RepoJoseph S. M. SamecNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019) |
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Science Q Rahul A. Watile Anon Bunrit Jèssica Margalef Sunisa Akkarasamiyo Rabia Ayub Emi Lagerspets Srijit Biswas Timo Repo Joseph S. M. Samec Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst |
description |
The direct substitution of the OH group of stereogenic alcohols are reported rarely in literature. Here, the authors demonstrate direct substitution of both secondary and tertiary alcohols with chirality transfer leading to enantioenriched 5-membered, 6-membered and aryl-fused 6-membered heterocyclic compounds. |
format |
article |
author |
Rahul A. Watile Anon Bunrit Jèssica Margalef Sunisa Akkarasamiyo Rabia Ayub Emi Lagerspets Srijit Biswas Timo Repo Joseph S. M. Samec |
author_facet |
Rahul A. Watile Anon Bunrit Jèssica Margalef Sunisa Akkarasamiyo Rabia Ayub Emi Lagerspets Srijit Biswas Timo Repo Joseph S. M. Samec |
author_sort |
Rahul A. Watile |
title |
Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst |
title_short |
Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst |
title_full |
Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst |
title_fullStr |
Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst |
title_full_unstemmed |
Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst |
title_sort |
intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(iii) catalyst |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/642177931c6547d3ba77fdf91901c007 |
work_keys_str_mv |
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