Novel Cellulose Derivatives Containing Metal (Cu, Fe, Ni) Oxide Nanoparticles as Eco-Friendly Corrosion Inhibitors for C-Steel in Acidic Chloride Solutions

Novel environmentally-friendly corrosion inhibitors based on primary aminated modified cellulose (PAC) containing nano-oxide of some metals (MONPs), for instance iron oxide nanoparticles (Fe<sub>3</sub>O<sub>4</sub>NPs), copper oxide nanoparticles (CuONPs), and nickel oxide n...

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Autores principales:	Mohamed Gouda, Hany M. Abd El-Lateef
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	cellulose derivatives corrosion inhibitors metal oxide nanoparticles cellulose nanocomposites Electrochemical Impedance Spectroscopy surface morphology Organic chemistry QD241-441
Acceso en línea:	https://doaj.org/article/6446ae6dbe424122988b76dded0dbc15
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spelling	oai:doaj.org-article:6446ae6dbe424122988b76dded0dbc152021-11-25T18:29:06ZNovel Cellulose Derivatives Containing Metal (Cu, Fe, Ni) Oxide Nanoparticles as Eco-Friendly Corrosion Inhibitors for C-Steel in Acidic Chloride Solutions10.3390/molecules262270061420-3049https://doaj.org/article/6446ae6dbe424122988b76dded0dbc152021-11-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/22/7006https://doaj.org/toc/1420-3049Novel environmentally-friendly corrosion inhibitors based on primary aminated modified cellulose (PAC) containing nano-oxide of some metals (MONPs), for instance iron oxide nanoparticles (Fe<sub>3</sub>O<sub>4</sub>NPs), copper oxide nanoparticles (CuONPs), and nickel oxide nanoparticles (NiONPs), were successfully synthesized. The as-prepared PAC/MONPs nanocomposites were categorized using Fourier transform infrared spectroscopy (FT-IR), transmission electron microscope (TEM), field-emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), and selected area diffraction pattern (SAED) techniques. The data from spectroscopy indicated that successful formation of PAC/MONPs nanocomposites, as well as the TEM images, declared the synthesized PAC/Fe<sub>3</sub>O<sub>4</sub>NPs, PAC/CuONPs, and PAC/NiONPs with regular distribution with particle size diameters of 10, 23 and 43 nm, respectively. The protection performance of the as-prepared PAC and PAC/MONPs nanocomposites on the corrosion of C-steel in molar HCl was studied by the electrochemical and weight-loss approaches. The outcomes confirmed that the protection power increased with a rise in the [inhibitor]. The protection efficiency reached 88.1, 93.2, 96.1 and 98.6% with 250 ppm of PAC/CuONP, PAC/Fe<sub>3</sub>O<sub>4</sub>NPs, and PAC/NiONPs, respectively. PAC and all PAC/MONPs nanocomposites worked as mixed-kind inhibitors and their adsorption on the C-steel interface followed the isotherm Langmuir model. The findings were reinforced by FT-IR, FE-SEM and EDX analyses.Mohamed GoudaHany M. Abd El-LateefMDPI AGarticlecellulose derivativescorrosion inhibitorsmetal oxide nanoparticlescellulose nanocompositesElectrochemical Impedance Spectroscopysurface morphologyOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 7006, p 7006 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	cellulose derivatives corrosion inhibitors metal oxide nanoparticles cellulose nanocomposites Electrochemical Impedance Spectroscopy surface morphology Organic chemistry QD241-441
spellingShingle	cellulose derivatives corrosion inhibitors metal oxide nanoparticles cellulose nanocomposites Electrochemical Impedance Spectroscopy surface morphology Organic chemistry QD241-441 Mohamed Gouda Hany M. Abd El-Lateef Novel Cellulose Derivatives Containing Metal (Cu, Fe, Ni) Oxide Nanoparticles as Eco-Friendly Corrosion Inhibitors for C-Steel in Acidic Chloride Solutions
description	Novel environmentally-friendly corrosion inhibitors based on primary aminated modified cellulose (PAC) containing nano-oxide of some metals (MONPs), for instance iron oxide nanoparticles (Fe<sub>3</sub>O<sub>4</sub>NPs), copper oxide nanoparticles (CuONPs), and nickel oxide nanoparticles (NiONPs), were successfully synthesized. The as-prepared PAC/MONPs nanocomposites were categorized using Fourier transform infrared spectroscopy (FT-IR), transmission electron microscope (TEM), field-emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), and selected area diffraction pattern (SAED) techniques. The data from spectroscopy indicated that successful formation of PAC/MONPs nanocomposites, as well as the TEM images, declared the synthesized PAC/Fe<sub>3</sub>O<sub>4</sub>NPs, PAC/CuONPs, and PAC/NiONPs with regular distribution with particle size diameters of 10, 23 and 43 nm, respectively. The protection performance of the as-prepared PAC and PAC/MONPs nanocomposites on the corrosion of C-steel in molar HCl was studied by the electrochemical and weight-loss approaches. The outcomes confirmed that the protection power increased with a rise in the [inhibitor]. The protection efficiency reached 88.1, 93.2, 96.1 and 98.6% with 250 ppm of PAC/CuONP, PAC/Fe<sub>3</sub>O<sub>4</sub>NPs, and PAC/NiONPs, respectively. PAC and all PAC/MONPs nanocomposites worked as mixed-kind inhibitors and their adsorption on the C-steel interface followed the isotherm Langmuir model. The findings were reinforced by FT-IR, FE-SEM and EDX analyses.
format	article
author	Mohamed Gouda Hany M. Abd El-Lateef
author_facet	Mohamed Gouda Hany M. Abd El-Lateef
author_sort	Mohamed Gouda
title	Novel Cellulose Derivatives Containing Metal (Cu, Fe, Ni) Oxide Nanoparticles as Eco-Friendly Corrosion Inhibitors for C-Steel in Acidic Chloride Solutions
title_short	Novel Cellulose Derivatives Containing Metal (Cu, Fe, Ni) Oxide Nanoparticles as Eco-Friendly Corrosion Inhibitors for C-Steel in Acidic Chloride Solutions
title_full	Novel Cellulose Derivatives Containing Metal (Cu, Fe, Ni) Oxide Nanoparticles as Eco-Friendly Corrosion Inhibitors for C-Steel in Acidic Chloride Solutions
title_fullStr	Novel Cellulose Derivatives Containing Metal (Cu, Fe, Ni) Oxide Nanoparticles as Eco-Friendly Corrosion Inhibitors for C-Steel in Acidic Chloride Solutions
title_full_unstemmed	Novel Cellulose Derivatives Containing Metal (Cu, Fe, Ni) Oxide Nanoparticles as Eco-Friendly Corrosion Inhibitors for C-Steel in Acidic Chloride Solutions
title_sort	novel cellulose derivatives containing metal (cu, fe, ni) oxide nanoparticles as eco-friendly corrosion inhibitors for c-steel in acidic chloride solutions
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/6446ae6dbe424122988b76dded0dbc15
work_keys_str_mv	AT mohamedgouda novelcellulosederivativescontainingmetalcufenioxidenanoparticlesasecofriendlycorrosioninhibitorsforcsteelinacidicchloridesolutions AT hanymabdellateef novelcellulosederivativescontainingmetalcufenioxidenanoparticlesasecofriendlycorrosioninhibitorsforcsteelinacidicchloridesolutions
_version_	1718411078694600704

Novel Cellulose Derivatives Containing Metal (Cu, Fe, Ni) Oxide Nanoparticles as Eco-Friendly Corrosion Inhibitors for C-Steel in Acidic Chloride Solutions

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