Direct observation of knock-on reaction with umbrella inversion arising from zero-impact-parameter collision at a surface

Collision geometries are hard to control, making transition states in chemical reaction hard to study. Here the authors show that a linear transition state leads to formation of reaction product ‘knocked-on’ along the continuation of the direction of reagent approach.

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Detalles Bibliográficos
Autores principales: Matthew J. Timm, Lydie Leung, Kelvin Anggara, John C. Polanyi
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/64844609c3944bac9f14e4474ddce823
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Descripción
Sumario:Collision geometries are hard to control, making transition states in chemical reaction hard to study. Here the authors show that a linear transition state leads to formation of reaction product ‘knocked-on’ along the continuation of the direction of reagent approach.