Direct observation of knock-on reaction with umbrella inversion arising from zero-impact-parameter collision at a surface

Collision geometries are hard to control, making transition states in chemical reaction hard to study. Here the authors show that a linear transition state leads to formation of reaction product ‘knocked-on’ along the continuation of the direction of reagent approach.

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Autores principales:	Matthew J. Timm, Lydie Leung, Kelvin Anggara, John C. Polanyi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/64844609c3944bac9f14e4474ddce823
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spelling	oai:doaj.org-article:64844609c3944bac9f14e4474ddce8232021-12-02T14:26:58ZDirect observation of knock-on reaction with umbrella inversion arising from zero-impact-parameter collision at a surface10.1038/s42004-021-00453-x2399-3669https://doaj.org/article/64844609c3944bac9f14e4474ddce8232021-02-01T00:00:00Zhttps://doi.org/10.1038/s42004-021-00453-xhttps://doaj.org/toc/2399-3669Collision geometries are hard to control, making transition states in chemical reaction hard to study. Here the authors show that a linear transition state leads to formation of reaction product ‘knocked-on’ along the continuation of the direction of reagent approach.Matthew J. TimmLydie LeungKelvin AnggaraJohn C. PolanyiNature PortfolioarticleChemistryQD1-999ENCommunications Chemistry, Vol 4, Iss 1, Pp 1-6 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Chemistry QD1-999
spellingShingle	Chemistry QD1-999 Matthew J. Timm Lydie Leung Kelvin Anggara John C. Polanyi Direct observation of knock-on reaction with umbrella inversion arising from zero-impact-parameter collision at a surface
description	Collision geometries are hard to control, making transition states in chemical reaction hard to study. Here the authors show that a linear transition state leads to formation of reaction product ‘knocked-on’ along the continuation of the direction of reagent approach.
format	article
author	Matthew J. Timm Lydie Leung Kelvin Anggara John C. Polanyi
author_facet	Matthew J. Timm Lydie Leung Kelvin Anggara John C. Polanyi
author_sort	Matthew J. Timm
title	Direct observation of knock-on reaction with umbrella inversion arising from zero-impact-parameter collision at a surface
title_short	Direct observation of knock-on reaction with umbrella inversion arising from zero-impact-parameter collision at a surface
title_full	Direct observation of knock-on reaction with umbrella inversion arising from zero-impact-parameter collision at a surface
title_fullStr	Direct observation of knock-on reaction with umbrella inversion arising from zero-impact-parameter collision at a surface
title_full_unstemmed	Direct observation of knock-on reaction with umbrella inversion arising from zero-impact-parameter collision at a surface
title_sort	direct observation of knock-on reaction with umbrella inversion arising from zero-impact-parameter collision at a surface
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/64844609c3944bac9f14e4474ddce823
work_keys_str_mv	AT matthewjtimm directobservationofknockonreactionwithumbrellainversionarisingfromzeroimpactparametercollisionatasurface AT lydieleung directobservationofknockonreactionwithumbrellainversionarisingfromzeroimpactparametercollisionatasurface AT kelvinanggara directobservationofknockonreactionwithumbrellainversionarisingfromzeroimpactparametercollisionatasurface AT johncpolanyi directobservationofknockonreactionwithumbrellainversionarisingfromzeroimpactparametercollisionatasurface
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Direct observation of knock-on reaction with umbrella inversion arising from zero-impact-parameter collision at a surface

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