Formal group insertion into aryl C‒N bonds through an aromaticity destruction-reconstruction process

Formal group insertion into aryl C‒N bonds through an aromaticity destruction-reconstruction process

Activation of C–N bonds of anilines requires transformation of the amino group into a more reactive functionality. Here, the authors report an aromaticity destruction-reconstruction process that converts abundant anilines into valuable amines through group insertion into the C–N bond and benzylic C–...

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Autores principales: Dandan Han, Qiuqin He, Renhua Fan
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/64f27b6d50a24572affe783994d2b747
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spelling oai:doaj.org-article:64f27b6d50a24572affe783994d2b7472021-12-02T16:49:56ZFormal group insertion into aryl C‒N bonds through an aromaticity destruction-reconstruction process10.1038/s41467-018-05637-z2041-1723https://doaj.org/article/64f27b6d50a24572affe783994d2b7472018-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-05637-zhttps://doaj.org/toc/2041-1723Activation of C–N bonds of anilines requires transformation of the amino group into a more reactive functionality. Here, the authors report an aromaticity destruction-reconstruction process that converts abundant anilines into valuable amines through group insertion into the C–N bond and benzylic C–H functionalization.Dandan HanQiuqin HeRenhua FanNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-7 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Dandan Han
Qiuqin He
Renhua Fan
Formal group insertion into aryl C‒N bonds through an aromaticity destruction-reconstruction process
description Activation of C–N bonds of anilines requires transformation of the amino group into a more reactive functionality. Here, the authors report an aromaticity destruction-reconstruction process that converts abundant anilines into valuable amines through group insertion into the C–N bond and benzylic C–H functionalization.
format article
author Dandan Han
Qiuqin He
Renhua Fan
author_facet Dandan Han
Qiuqin He
Renhua Fan
author_sort Dandan Han
title Formal group insertion into aryl C‒N bonds through an aromaticity destruction-reconstruction process
title_short Formal group insertion into aryl C‒N bonds through an aromaticity destruction-reconstruction process
title_full Formal group insertion into aryl C‒N bonds through an aromaticity destruction-reconstruction process
title_fullStr Formal group insertion into aryl C‒N bonds through an aromaticity destruction-reconstruction process
title_full_unstemmed Formal group insertion into aryl C‒N bonds through an aromaticity destruction-reconstruction process
title_sort formal group insertion into aryl c‒n bonds through an aromaticity destruction-reconstruction process
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/64f27b6d50a24572affe783994d2b747
work_keys_str_mv AT dandanhan formalgroupinsertionintoarylcnbondsthroughanaromaticitydestructionreconstructionprocess
AT qiuqinhe formalgroupinsertionintoarylcnbondsthroughanaromaticitydestructionreconstructionprocess
AT renhuafan formalgroupinsertionintoarylcnbondsthroughanaromaticitydestructionreconstructionprocess
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