Formal group insertion into aryl C‒N bonds through an aromaticity destruction-reconstruction process
Activation of C–N bonds of anilines requires transformation of the amino group into a more reactive functionality. Here, the authors report an aromaticity destruction-reconstruction process that converts abundant anilines into valuable amines through group insertion into the C–N bond and benzylic C–...
Guardado en:
Autores principales: | Dandan Han, Qiuqin He, Renhua Fan |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2018
|
Materias: | |
Acceso en línea: | https://doaj.org/article/64f27b6d50a24572affe783994d2b747 |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
Ejemplares similares
-
Conversion of anilines to chiral benzylic amines via formal one-carbon insertion into aromatic C–N bonds
por: Lei Li, et al.
Publicado: (2020) -
Transition-metal-free formal cross-coupling of aryl methyl sulfoxides and alcohols via nucleophilic activation of C-S bond
por: Guolin Li, et al.
Publicado: (2020) -
Palladium-catalyzed α-arylation for the addition of small rings to aromatic compounds
por: Zhi-Tao He, et al.
Publicado: (2019) -
Rhodium(II)-catalyzed multicomponent assembly of α,α,α-trisubstituted esters via formal insertion of O–C(sp3)–C(sp2) into C–C bonds
por: Dan Ba, et al.
Publicado: (2020) -
Thioketone-directed rhodium(I) catalyzed enantioselective C-H bond arylation of ferrocenes
por: Zhong-Jian Cai, et al.
Publicado: (2019)