Geochemical and organic petrographic characteristics of high bituminous shales from Gurha mine in Rajasthan, NW India

Abstract A high bituminous shale horizon from the Gurha mine in the Bikaner sub-basin of the Rajasthan District, NW India, was studied using a collection of geochemical and petrological techniques. This study investigated the nature and environmental conditions of the organic matter and its relation...

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Autores principales: Alok K. Singh, Mohammed Hail Hakimi, Alok Kumar, Adeeb Ahmed, Nor Syazwani Zainal Abidin, Mostafa Kinawy, Osama El Mahdy, Aref Lashin
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Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/64fad8d0cbb0484182a8698f9f0869e3
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spelling oai:doaj.org-article:64fad8d0cbb0484182a8698f9f0869e32021-12-02T13:34:09ZGeochemical and organic petrographic characteristics of high bituminous shales from Gurha mine in Rajasthan, NW India10.1038/s41598-020-78906-x2045-2322https://doaj.org/article/64fad8d0cbb0484182a8698f9f0869e32020-12-01T00:00:00Zhttps://doi.org/10.1038/s41598-020-78906-xhttps://doaj.org/toc/2045-2322Abstract A high bituminous shale horizon from the Gurha mine in the Bikaner sub-basin of the Rajasthan District, NW India, was studied using a collection of geochemical and petrological techniques. This study investigated the nature and environmental conditions of the organic matter and its relation to the unconventional oil-shale resources of the bituminous shale. The analyzed shales have high total organic carbon and total sulfur contents, suggesting that these shale sediments were deposited in a paralic environment under reducing conditions. The dominant presence of organic matter derived from phytoplankton algae suggests warm climatic marine environment, with little connection to freshwater enhancing the growth of algae and other microorganisms. The analyzed bituminous shales have high aquatic-derived alginite organic matters, with low Pr/Ph, Pr/n-C17, and Ph/n-C18 ratios. It is classified as Type II oil-prone kerogen, consistent with high hydrogen index value. Considering the maturity indicators of geochemical Tmax (< 430 °C) and vitrinite reflectance values less than 0.40%VRo, the analyzed bituminous shale sediments are in an immature stage of the oil window. Therefore, the oil-prone kerogen Type II in the analyzed bituminous shales has not been cracked by thermal alteration to release oil; thus, unconventional heating is recommended for commercial oil generation.Alok K. SinghMohammed Hail HakimiAlok KumarAdeeb AhmedNor Syazwani Zainal AbidinMostafa KinawyOsama El MahdyAref LashinNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 10, Iss 1, Pp 1-19 (2020)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Alok K. Singh
Mohammed Hail Hakimi
Alok Kumar
Adeeb Ahmed
Nor Syazwani Zainal Abidin
Mostafa Kinawy
Osama El Mahdy
Aref Lashin
Geochemical and organic petrographic characteristics of high bituminous shales from Gurha mine in Rajasthan, NW India
description Abstract A high bituminous shale horizon from the Gurha mine in the Bikaner sub-basin of the Rajasthan District, NW India, was studied using a collection of geochemical and petrological techniques. This study investigated the nature and environmental conditions of the organic matter and its relation to the unconventional oil-shale resources of the bituminous shale. The analyzed shales have high total organic carbon and total sulfur contents, suggesting that these shale sediments were deposited in a paralic environment under reducing conditions. The dominant presence of organic matter derived from phytoplankton algae suggests warm climatic marine environment, with little connection to freshwater enhancing the growth of algae and other microorganisms. The analyzed bituminous shales have high aquatic-derived alginite organic matters, with low Pr/Ph, Pr/n-C17, and Ph/n-C18 ratios. It is classified as Type II oil-prone kerogen, consistent with high hydrogen index value. Considering the maturity indicators of geochemical Tmax (< 430 °C) and vitrinite reflectance values less than 0.40%VRo, the analyzed bituminous shale sediments are in an immature stage of the oil window. Therefore, the oil-prone kerogen Type II in the analyzed bituminous shales has not been cracked by thermal alteration to release oil; thus, unconventional heating is recommended for commercial oil generation.
format article
author Alok K. Singh
Mohammed Hail Hakimi
Alok Kumar
Adeeb Ahmed
Nor Syazwani Zainal Abidin
Mostafa Kinawy
Osama El Mahdy
Aref Lashin
author_facet Alok K. Singh
Mohammed Hail Hakimi
Alok Kumar
Adeeb Ahmed
Nor Syazwani Zainal Abidin
Mostafa Kinawy
Osama El Mahdy
Aref Lashin
author_sort Alok K. Singh
title Geochemical and organic petrographic characteristics of high bituminous shales from Gurha mine in Rajasthan, NW India
title_short Geochemical and organic petrographic characteristics of high bituminous shales from Gurha mine in Rajasthan, NW India
title_full Geochemical and organic petrographic characteristics of high bituminous shales from Gurha mine in Rajasthan, NW India
title_fullStr Geochemical and organic petrographic characteristics of high bituminous shales from Gurha mine in Rajasthan, NW India
title_full_unstemmed Geochemical and organic petrographic characteristics of high bituminous shales from Gurha mine in Rajasthan, NW India
title_sort geochemical and organic petrographic characteristics of high bituminous shales from gurha mine in rajasthan, nw india
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/64fad8d0cbb0484182a8698f9f0869e3
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