Physical Intuition to Improve Electronic Properties of Thermoelectrics
Thermoelectrics convert heat to electricity and vice versa. They are of technological importance in cooling and energy harvesting. Their performances are defined by figure of merit, zT. Decades of studies have largely focused on the development of novel and advanced materials reaching higher perform...
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Frontiers Media S.A.
2021
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oai:doaj.org-article:652b974f2a874e108e761103755a58e42021-12-01T10:52:40ZPhysical Intuition to Improve Electronic Properties of Thermoelectrics2296-424X10.3389/fphy.2021.755597https://doaj.org/article/652b974f2a874e108e761103755a58e42021-11-01T00:00:00Zhttps://www.frontiersin.org/articles/10.3389/fphy.2021.755597/fullhttps://doaj.org/toc/2296-424XThermoelectrics convert heat to electricity and vice versa. They are of technological importance in cooling and energy harvesting. Their performances are defined by figure of merit, zT. Decades of studies have largely focused on the development of novel and advanced materials reaching higher performance in devices. To date, the lack of sufficiently high-performance thermoelectrics, especially among Earth-abundant and lightweight materials, is one of the reasons why there is no broad commercial application of thermoelectric devices yet. This challenge is due to the complex correlations of parameters that make up the zT. Theoretical estimation can reveal the optimal charge carrier concentration, which can provide a good idea of doping compositions. Depending on the material characteristics, decoupling these intercorrelated parameters could be viable. Broadly speaking, increasing carrier mobility, inducing a large fluctuation in density of states (DOS) at the Fermi level, and lowering the lattice thermal conductivity lead to better thermoelectric performance. In this mini review, we provide a broad picture of electronic property optimization for thermoelectric materials. This work will be a useful guide to quickly take readers to the forefront of thermoelectric research.Wei Yang Samuel LimDanwei ZhangSolco Samantha Faye DuranXian Yi TanChee Kiang Ivan TanJianwei XuAdy SuwardiAdy SuwardiFrontiers Media S.A.articlethermoelectricsthermal transportelectronic transportsemiconductorenergy harvestingPhysicsQC1-999ENFrontiers in Physics, Vol 9 (2021) |
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thermoelectrics thermal transport electronic transport semiconductor energy harvesting Physics QC1-999 |
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thermoelectrics thermal transport electronic transport semiconductor energy harvesting Physics QC1-999 Wei Yang Samuel Lim Danwei Zhang Solco Samantha Faye Duran Xian Yi Tan Chee Kiang Ivan Tan Jianwei Xu Ady Suwardi Ady Suwardi Physical Intuition to Improve Electronic Properties of Thermoelectrics |
description |
Thermoelectrics convert heat to electricity and vice versa. They are of technological importance in cooling and energy harvesting. Their performances are defined by figure of merit, zT. Decades of studies have largely focused on the development of novel and advanced materials reaching higher performance in devices. To date, the lack of sufficiently high-performance thermoelectrics, especially among Earth-abundant and lightweight materials, is one of the reasons why there is no broad commercial application of thermoelectric devices yet. This challenge is due to the complex correlations of parameters that make up the zT. Theoretical estimation can reveal the optimal charge carrier concentration, which can provide a good idea of doping compositions. Depending on the material characteristics, decoupling these intercorrelated parameters could be viable. Broadly speaking, increasing carrier mobility, inducing a large fluctuation in density of states (DOS) at the Fermi level, and lowering the lattice thermal conductivity lead to better thermoelectric performance. In this mini review, we provide a broad picture of electronic property optimization for thermoelectric materials. This work will be a useful guide to quickly take readers to the forefront of thermoelectric research. |
format |
article |
author |
Wei Yang Samuel Lim Danwei Zhang Solco Samantha Faye Duran Xian Yi Tan Chee Kiang Ivan Tan Jianwei Xu Ady Suwardi Ady Suwardi |
author_facet |
Wei Yang Samuel Lim Danwei Zhang Solco Samantha Faye Duran Xian Yi Tan Chee Kiang Ivan Tan Jianwei Xu Ady Suwardi Ady Suwardi |
author_sort |
Wei Yang Samuel Lim |
title |
Physical Intuition to Improve Electronic Properties of Thermoelectrics |
title_short |
Physical Intuition to Improve Electronic Properties of Thermoelectrics |
title_full |
Physical Intuition to Improve Electronic Properties of Thermoelectrics |
title_fullStr |
Physical Intuition to Improve Electronic Properties of Thermoelectrics |
title_full_unstemmed |
Physical Intuition to Improve Electronic Properties of Thermoelectrics |
title_sort |
physical intuition to improve electronic properties of thermoelectrics |
publisher |
Frontiers Media S.A. |
publishDate |
2021 |
url |
https://doaj.org/article/652b974f2a874e108e761103755a58e4 |
work_keys_str_mv |
AT weiyangsamuellim physicalintuitiontoimproveelectronicpropertiesofthermoelectrics AT danweizhang physicalintuitiontoimproveelectronicpropertiesofthermoelectrics AT solcosamanthafayeduran physicalintuitiontoimproveelectronicpropertiesofthermoelectrics AT xianyitan physicalintuitiontoimproveelectronicpropertiesofthermoelectrics AT cheekiangivantan physicalintuitiontoimproveelectronicpropertiesofthermoelectrics AT jianweixu physicalintuitiontoimproveelectronicpropertiesofthermoelectrics AT adysuwardi physicalintuitiontoimproveelectronicpropertiesofthermoelectrics AT adysuwardi physicalintuitiontoimproveelectronicpropertiesofthermoelectrics |
_version_ |
1718405237166833664 |