Electrochemical C–N bond activation for deaminative reductive coupling of Katritzky salts

Electrochemical transformations use electrons and electron holes instead of chemical oxidants and reductants as reagents. Here, the authors report an electrochemical reductive deaminative cross-coupling of Katrizky salts with various radical acceptors, including examples of fluoroalkenylation, alkyn...

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Autores principales: Yeqing Liu, Xiangzhang Tao, Yu Mao, Xin Yuan, Jiangkai Qiu, Linyu Kong, Shengyang Ni, Kai Guo, Yi Wang, Yi Pan
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/65c1407ac8ad4da8b04cbbba29702ef5
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Sumario:Electrochemical transformations use electrons and electron holes instead of chemical oxidants and reductants as reagents. Here, the authors report an electrochemical reductive deaminative cross-coupling of Katrizky salts with various radical acceptors, including examples of fluoroalkenylation, alkynylation and thiolation.