Stepwise on-surface dissymmetric reaction to construct binodal organometallic network
Dissymmetric functionalization of equivalent sites in a molecule is a synthetic challenge. Here, the authors achieve an on-surface dissymmetric reaction of a molecular precursor through stepwise activation of its identical functional groups, leading to the formation of a 2D organometallic network wi...
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Nature Portfolio
2019
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oai:doaj.org-article:65f6f4cb96e74e928c18588638523e7b2021-12-02T16:58:29ZStepwise on-surface dissymmetric reaction to construct binodal organometallic network10.1038/s41467-019-10522-42041-1723https://doaj.org/article/65f6f4cb96e74e928c18588638523e7b2019-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-10522-4https://doaj.org/toc/2041-1723Dissymmetric functionalization of equivalent sites in a molecule is a synthetic challenge. Here, the authors achieve an on-surface dissymmetric reaction of a molecular precursor through stepwise activation of its identical functional groups, leading to the formation of a 2D organometallic network with two types of nodes.Jing LiuQiwei ChenKang CaiJie LiYaru LiXiao YangYajie ZhangYongfeng WangHao TangDahui ZhaoKai WuNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019) |
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Science Q Jing Liu Qiwei Chen Kang Cai Jie Li Yaru Li Xiao Yang Yajie Zhang Yongfeng Wang Hao Tang Dahui Zhao Kai Wu Stepwise on-surface dissymmetric reaction to construct binodal organometallic network |
description |
Dissymmetric functionalization of equivalent sites in a molecule is a synthetic challenge. Here, the authors achieve an on-surface dissymmetric reaction of a molecular precursor through stepwise activation of its identical functional groups, leading to the formation of a 2D organometallic network with two types of nodes. |
format |
article |
author |
Jing Liu Qiwei Chen Kang Cai Jie Li Yaru Li Xiao Yang Yajie Zhang Yongfeng Wang Hao Tang Dahui Zhao Kai Wu |
author_facet |
Jing Liu Qiwei Chen Kang Cai Jie Li Yaru Li Xiao Yang Yajie Zhang Yongfeng Wang Hao Tang Dahui Zhao Kai Wu |
author_sort |
Jing Liu |
title |
Stepwise on-surface dissymmetric reaction to construct binodal organometallic network |
title_short |
Stepwise on-surface dissymmetric reaction to construct binodal organometallic network |
title_full |
Stepwise on-surface dissymmetric reaction to construct binodal organometallic network |
title_fullStr |
Stepwise on-surface dissymmetric reaction to construct binodal organometallic network |
title_full_unstemmed |
Stepwise on-surface dissymmetric reaction to construct binodal organometallic network |
title_sort |
stepwise on-surface dissymmetric reaction to construct binodal organometallic network |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/65f6f4cb96e74e928c18588638523e7b |
work_keys_str_mv |
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_version_ |
1718382269549248512 |