Molecular and electronic structure of terminal and alkali metal-capped uranium(V) nitride complexes
Actinide electronic structure determination is fundamentally challenging. Here, the authors assemble a family of uranium(V)-nitrides and quantify the electronic structure of the molecules, defining the relative importance of spin orbit coupling and crystal field interactions.
Guardado en:
Autores principales: | David M. King, Peter A. Cleaves, Ashley J. Wooles, Benedict M. Gardner, Nicholas F. Chilton, Floriana Tuna, William Lewis, Eric J. L. McInnes, Stephen T. Liddle |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2016
|
Materias: | |
Acceso en línea: | https://doaj.org/article/66f8a8d3e96e426c8bc9a7569f50dc52 |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
Ejemplares similares
-
Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms
por: Lucile Chatelain, et al.
Publicado: (2020) -
Evidence for single metal two electron oxidative addition and reductive elimination at uranium
por: Benedict M. Gardner, et al.
Publicado: (2017) -
Evidence for ligand- and solvent-induced disproportionation of uranium(IV)
por: Jingzhen Du, et al.
Publicado: (2021) -
Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings
por: Ashley J. Wooles, et al.
Publicado: (2018) -
Exceptional uranium(VI)-nitride triple bond covalency from 15N nuclear magnetic resonance spectroscopy and quantum chemical analysis
por: Jingzhen Du, et al.
Publicado: (2021)