Acoustic-optical phonon up-conversion and hot-phonon bottleneck in lead-halide perovskites

Slow cooling of hot charge carriers in lead halide perovskite could be used in photovoltaics devices. Here, Yanget al. study hot carrier dynamics by transient absorption spectroscopy. They relate the phonon bottleneck to the up-conversion of low-energy phonons, facilitated by the presence of organic...

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Autores principales: Jianfeng Yang, Xiaoming Wen, Hongze Xia, Rui Sheng, Qingshan Ma, Jincheol Kim, Patrick Tapping, Takaaki Harada, Tak W. Kee, Fuzhi Huang, Yi-Bing Cheng, Martin Green, Anita Ho-Baillie, Shujuan Huang, Santosh Shrestha, Robert Patterson, Gavin Conibeer
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/67679770d2034343ac6e71fbcd18feab
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Sumario:Slow cooling of hot charge carriers in lead halide perovskite could be used in photovoltaics devices. Here, Yanget al. study hot carrier dynamics by transient absorption spectroscopy. They relate the phonon bottleneck to the up-conversion of low-energy phonons, facilitated by the presence of organic cations.