Penentuan Resistivitas Tak-Terkompensasi Cairan Ion Berbasis Imidazol dengan Metode EIS: Pengaruh Panjang Alkil dan Perbedaan Anion

Ionic liquids have interesting properties because they have several advantages compared to conventional organic solvents, such as high thermal stability, high viscosity, good solvent properties, non-flammable, and non-volatile. In electrochemistry, ionic liquids can be used as solvents without the a...

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Autores principales: Aep Patah, Yulia Rachmawati, Riyadini Utari, Achmad Rochliadi
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Publicado: Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Andalas 2020
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Acceso en línea:https://doaj.org/article/67a50b3d581c42aa884c11a6fedd8414
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spelling oai:doaj.org-article:67a50b3d581c42aa884c11a6fedd84142021-12-02T11:09:53ZPenentuan Resistivitas Tak-Terkompensasi Cairan Ion Berbasis Imidazol dengan Metode EIS: Pengaruh Panjang Alkil dan Perbedaan Anion1978-628X2476-896010.25077/jrk.v11i2.359https://doaj.org/article/67a50b3d581c42aa884c11a6fedd84142020-08-01T00:00:00Zhttp://jrk.fmipa.unand.ac.id/index.php/jrk/article/view/359https://doaj.org/toc/1978-628Xhttps://doaj.org/toc/2476-8960Ionic liquids have interesting properties because they have several advantages compared to conventional organic solvents, such as high thermal stability, high viscosity, good solvent properties, non-flammable, and non-volatile. In electrochemistry, ionic liquids can be used as solvents without the addition of electrolytes. However, ionic liquids still have resistivity properties (uncompensated resistance), thus ohmic drop measurements are needed for a potential correction. Imidazole-based ionic liquids, which are known for their high conductivity and commonly used as a solvent, have been measured of their resistivity as a function of temperature, and type of their cations/anions. Electrochemical Impedance Spectroscopy (EIS) method was chosen to measure the resistivity of ionic liquids and Bode plot was generated for the analysis of the results. The measured resistivities of ionic liquids are in the range of 420 to 1500 ohm. It is concluded that the resistivity of the imidazole-based ionic liquid is influenced by the size of their constituent ions, the viscosity, and the resistance is decreased with increasing temperature.Aep PatahYulia RachmawatiRiyadini UtariAchmad RochliadiDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Andalasarticleionic liquidsuncompensated resistanceeisimidazolebode plotChemistryQD1-999BiochemistryQD415-436ENIDJurnal Riset Kimia, Vol 11, Iss 2, Pp 106-112 (2020)
institution DOAJ
collection DOAJ
language EN
ID
topic ionic liquids
uncompensated resistance
eis
imidazole
bode plot
Chemistry
QD1-999
Biochemistry
QD415-436
spellingShingle ionic liquids
uncompensated resistance
eis
imidazole
bode plot
Chemistry
QD1-999
Biochemistry
QD415-436
Aep Patah
Yulia Rachmawati
Riyadini Utari
Achmad Rochliadi
Penentuan Resistivitas Tak-Terkompensasi Cairan Ion Berbasis Imidazol dengan Metode EIS: Pengaruh Panjang Alkil dan Perbedaan Anion
description Ionic liquids have interesting properties because they have several advantages compared to conventional organic solvents, such as high thermal stability, high viscosity, good solvent properties, non-flammable, and non-volatile. In electrochemistry, ionic liquids can be used as solvents without the addition of electrolytes. However, ionic liquids still have resistivity properties (uncompensated resistance), thus ohmic drop measurements are needed for a potential correction. Imidazole-based ionic liquids, which are known for their high conductivity and commonly used as a solvent, have been measured of their resistivity as a function of temperature, and type of their cations/anions. Electrochemical Impedance Spectroscopy (EIS) method was chosen to measure the resistivity of ionic liquids and Bode plot was generated for the analysis of the results. The measured resistivities of ionic liquids are in the range of 420 to 1500 ohm. It is concluded that the resistivity of the imidazole-based ionic liquid is influenced by the size of their constituent ions, the viscosity, and the resistance is decreased with increasing temperature.
format article
author Aep Patah
Yulia Rachmawati
Riyadini Utari
Achmad Rochliadi
author_facet Aep Patah
Yulia Rachmawati
Riyadini Utari
Achmad Rochliadi
author_sort Aep Patah
title Penentuan Resistivitas Tak-Terkompensasi Cairan Ion Berbasis Imidazol dengan Metode EIS: Pengaruh Panjang Alkil dan Perbedaan Anion
title_short Penentuan Resistivitas Tak-Terkompensasi Cairan Ion Berbasis Imidazol dengan Metode EIS: Pengaruh Panjang Alkil dan Perbedaan Anion
title_full Penentuan Resistivitas Tak-Terkompensasi Cairan Ion Berbasis Imidazol dengan Metode EIS: Pengaruh Panjang Alkil dan Perbedaan Anion
title_fullStr Penentuan Resistivitas Tak-Terkompensasi Cairan Ion Berbasis Imidazol dengan Metode EIS: Pengaruh Panjang Alkil dan Perbedaan Anion
title_full_unstemmed Penentuan Resistivitas Tak-Terkompensasi Cairan Ion Berbasis Imidazol dengan Metode EIS: Pengaruh Panjang Alkil dan Perbedaan Anion
title_sort penentuan resistivitas tak-terkompensasi cairan ion berbasis imidazol dengan metode eis: pengaruh panjang alkil dan perbedaan anion
publisher Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Andalas
publishDate 2020
url https://doaj.org/article/67a50b3d581c42aa884c11a6fedd8414
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