Emergence of the structure-directing role of f-orbital overlap-driven covalency

In actinide chemistry, a longstanding bonding model describes metal-ligand binding using 6d-orbitals, with the 5f-orbitals remaining non-bonding. Here the authors explore the inverse-trans-influence — a case where the model breaks down — finding that the f-orbitals play a crucial role in dictating a...

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Autores principales:	Erli Lu, Saira Sajjad, Victoria E. J. Berryman, Ashley J. Wooles, Nikolas Kaltsoyannis, Stephen T. Liddle
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/67caa517e6ee41fea7114dc4bd016540
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spelling	oai:doaj.org-article:67caa517e6ee41fea7114dc4bd0165402021-12-02T16:57:06ZEmergence of the structure-directing role of f-orbital overlap-driven covalency10.1038/s41467-019-08553-y2041-1723https://doaj.org/article/67caa517e6ee41fea7114dc4bd0165402019-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08553-yhttps://doaj.org/toc/2041-1723In actinide chemistry, a longstanding bonding model describes metal-ligand binding using 6d-orbitals, with the 5f-orbitals remaining non-bonding. Here the authors explore the inverse-trans-influence — a case where the model breaks down — finding that the f-orbitals play a crucial role in dictating a trans-ligand-directed geometry.Erli LuSaira SajjadVictoria E. J. BerrymanAshley J. WoolesNikolas KaltsoyannisStephen T. LiddleNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Erli Lu Saira Sajjad Victoria E. J. Berryman Ashley J. Wooles Nikolas Kaltsoyannis Stephen T. Liddle Emergence of the structure-directing role of f-orbital overlap-driven covalency
description	In actinide chemistry, a longstanding bonding model describes metal-ligand binding using 6d-orbitals, with the 5f-orbitals remaining non-bonding. Here the authors explore the inverse-trans-influence — a case where the model breaks down — finding that the f-orbitals play a crucial role in dictating a trans-ligand-directed geometry.
format	article
author	Erli Lu Saira Sajjad Victoria E. J. Berryman Ashley J. Wooles Nikolas Kaltsoyannis Stephen T. Liddle
author_facet	Erli Lu Saira Sajjad Victoria E. J. Berryman Ashley J. Wooles Nikolas Kaltsoyannis Stephen T. Liddle
author_sort	Erli Lu
title	Emergence of the structure-directing role of f-orbital overlap-driven covalency
title_short	Emergence of the structure-directing role of f-orbital overlap-driven covalency
title_full	Emergence of the structure-directing role of f-orbital overlap-driven covalency
title_fullStr	Emergence of the structure-directing role of f-orbital overlap-driven covalency
title_full_unstemmed	Emergence of the structure-directing role of f-orbital overlap-driven covalency
title_sort	emergence of the structure-directing role of f-orbital overlap-driven covalency
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/67caa517e6ee41fea7114dc4bd016540
work_keys_str_mv	AT erlilu emergenceofthestructuredirectingroleofforbitaloverlapdrivencovalency AT sairasajjad emergenceofthestructuredirectingroleofforbitaloverlapdrivencovalency AT victoriaejberryman emergenceofthestructuredirectingroleofforbitaloverlapdrivencovalency AT ashleyjwooles emergenceofthestructuredirectingroleofforbitaloverlapdrivencovalency AT nikolaskaltsoyannis emergenceofthestructuredirectingroleofforbitaloverlapdrivencovalency AT stephentliddle emergenceofthestructuredirectingroleofforbitaloverlapdrivencovalency
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Emergence of the structure-directing role of f-orbital overlap-driven covalency

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