Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation

The Co-catalysed hydroformylation of olefins produces selectively linear but not branched aldehydes. Here, the authors show that microporous MOFs increase the olefins density in the pores beyond neat conditions allowing high branched selectivity through kinetic modulation when added to a liquid phas...

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Autores principales:	Gerald Bauer, Daniele Ongari, Davide Tiana, Patrick Gäumann, Thomas Rohrbach, Gerard Pareras, Mohamed Tarik, Berend Smit, Marco Ranocchiari
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/6810a322a4eb42448c097c9a3a0171db
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spelling	oai:doaj.org-article:6810a322a4eb42448c097c9a3a0171db2021-12-02T17:32:41ZMetal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation10.1038/s41467-020-14828-62041-1723https://doaj.org/article/6810a322a4eb42448c097c9a3a0171db2020-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-14828-6https://doaj.org/toc/2041-1723The Co-catalysed hydroformylation of olefins produces selectively linear but not branched aldehydes. Here, the authors show that microporous MOFs increase the olefins density in the pores beyond neat conditions allowing high branched selectivity through kinetic modulation when added to a liquid phase hydroformylation mixture.Gerald BauerDaniele OngariDavide TianaPatrick GäumannThomas RohrbachGerard ParerasMohamed TarikBerend SmitMarco RanocchiariNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Gerald Bauer Daniele Ongari Davide Tiana Patrick Gäumann Thomas Rohrbach Gerard Pareras Mohamed Tarik Berend Smit Marco Ranocchiari Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation
description	The Co-catalysed hydroformylation of olefins produces selectively linear but not branched aldehydes. Here, the authors show that microporous MOFs increase the olefins density in the pores beyond neat conditions allowing high branched selectivity through kinetic modulation when added to a liquid phase hydroformylation mixture.
format	article
author	Gerald Bauer Daniele Ongari Davide Tiana Patrick Gäumann Thomas Rohrbach Gerard Pareras Mohamed Tarik Berend Smit Marco Ranocchiari
author_facet	Gerald Bauer Daniele Ongari Davide Tiana Patrick Gäumann Thomas Rohrbach Gerard Pareras Mohamed Tarik Berend Smit Marco Ranocchiari
author_sort	Gerald Bauer
title	Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation
title_short	Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation
title_full	Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation
title_fullStr	Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation
title_full_unstemmed	Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation
title_sort	metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/6810a322a4eb42448c097c9a3a0171db
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Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation

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