Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation

Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation

The Co-catalysed hydroformylation of olefins produces selectively linear but not branched aldehydes. Here, the authors show that microporous MOFs increase the olefins density in the pores beyond neat conditions allowing high branched selectivity through kinetic modulation when added to a liquid phas...

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Autores principales: Gerald Bauer, Daniele Ongari, Davide Tiana, Patrick Gäumann, Thomas Rohrbach, Gerard Pareras, Mohamed Tarik, Berend Smit, Marco Ranocchiari
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Science
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Acceso en línea:https://doaj.org/article/6810a322a4eb42448c097c9a3a0171db
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