Atom-economic catalytic amide synthesis from amines and carboxylic acids activated in situ with acetylenes

Amide formation is a ubiquitous reaction in organic chemistry, but suffers from the problem of generating large amounts of waste. Here, the authors report a catalytic amide synthesis by the ruthenium catalysed addition of carboxylic acids to acetylenes, followed by reaction with primary or secondary...

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Autores principales:	Thilo Krause, Sabrina Baader, Benjamin Erb, Lukas J. Gooßen
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/68da9c19f6924ffc9968ed44e9e56cf5
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spelling	oai:doaj.org-article:68da9c19f6924ffc9968ed44e9e56cf52021-12-02T17:33:07ZAtom-economic catalytic amide synthesis from amines and carboxylic acids activated in situ with acetylenes10.1038/ncomms117322041-1723https://doaj.org/article/68da9c19f6924ffc9968ed44e9e56cf52016-06-01T00:00:00Zhttps://doi.org/10.1038/ncomms11732https://doaj.org/toc/2041-1723Amide formation is a ubiquitous reaction in organic chemistry, but suffers from the problem of generating large amounts of waste. Here, the authors report a catalytic amide synthesis by the ruthenium catalysed addition of carboxylic acids to acetylenes, followed by reaction with primary or secondary amines.Thilo KrauseSabrina BaaderBenjamin ErbLukas J. GooßenNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-7 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Thilo Krause Sabrina Baader Benjamin Erb Lukas J. Gooßen Atom-economic catalytic amide synthesis from amines and carboxylic acids activated in situ with acetylenes
description	Amide formation is a ubiquitous reaction in organic chemistry, but suffers from the problem of generating large amounts of waste. Here, the authors report a catalytic amide synthesis by the ruthenium catalysed addition of carboxylic acids to acetylenes, followed by reaction with primary or secondary amines.
format	article
author	Thilo Krause Sabrina Baader Benjamin Erb Lukas J. Gooßen
author_facet	Thilo Krause Sabrina Baader Benjamin Erb Lukas J. Gooßen
author_sort	Thilo Krause
title	Atom-economic catalytic amide synthesis from amines and carboxylic acids activated in situ with acetylenes
title_short	Atom-economic catalytic amide synthesis from amines and carboxylic acids activated in situ with acetylenes
title_full	Atom-economic catalytic amide synthesis from amines and carboxylic acids activated in situ with acetylenes
title_fullStr	Atom-economic catalytic amide synthesis from amines and carboxylic acids activated in situ with acetylenes
title_full_unstemmed	Atom-economic catalytic amide synthesis from amines and carboxylic acids activated in situ with acetylenes
title_sort	atom-economic catalytic amide synthesis from amines and carboxylic acids activated in situ with acetylenes
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/68da9c19f6924ffc9968ed44e9e56cf5
work_keys_str_mv	AT thilokrause atomeconomiccatalyticamidesynthesisfromaminesandcarboxylicacidsactivatedinsituwithacetylenes AT sabrinabaader atomeconomiccatalyticamidesynthesisfromaminesandcarboxylicacidsactivatedinsituwithacetylenes AT benjaminerb atomeconomiccatalyticamidesynthesisfromaminesandcarboxylicacidsactivatedinsituwithacetylenes AT lukasjgooßen atomeconomiccatalyticamidesynthesisfromaminesandcarboxylicacidsactivatedinsituwithacetylenes
_version_	1718380065556791296

Atom-economic catalytic amide synthesis from amines and carboxylic acids activated in situ with acetylenes

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