Optimizing reaction paths for methanol synthesis from CO2 hydrogenation via metal-ligand cooperativity

Controlling the reaction path is instrumental for developing efficient catalysts for CO2 hydrogenation. Here, the authors report that the ensemble of Pt single atoms coordinated with oxygen atoms in MIL-101 induces distinct reaction path to improve selective hydrogenation of CO2 into methanol relati...

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Autores principales:	Yizhen Chen, Hongliang Li, Wanghui Zhao, Wenbo Zhang, Jiawei Li, Wei Li, Xusheng Zheng, Wensheng Yan, Wenhua Zhang, Junfa Zhu, Rui Si, Jie Zeng
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/696dbb8bda864e5b9662e05a6e332a6c
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spelling	oai:doaj.org-article:696dbb8bda864e5b9662e05a6e332a6c2021-12-02T14:35:37ZOptimizing reaction paths for methanol synthesis from CO2 hydrogenation via metal-ligand cooperativity10.1038/s41467-019-09918-z2041-1723https://doaj.org/article/696dbb8bda864e5b9662e05a6e332a6c2019-04-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-09918-zhttps://doaj.org/toc/2041-1723Controlling the reaction path is instrumental for developing efficient catalysts for CO2 hydrogenation. Here, the authors report that the ensemble of Pt single atoms coordinated with oxygen atoms in MIL-101 induces distinct reaction path to improve selective hydrogenation of CO2 into methanol relative to nanocrystal counterparts.Yizhen ChenHongliang LiWanghui ZhaoWenbo ZhangJiawei LiWei LiXusheng ZhengWensheng YanWenhua ZhangJunfa ZhuRui SiJie ZengNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yizhen Chen Hongliang Li Wanghui Zhao Wenbo Zhang Jiawei Li Wei Li Xusheng Zheng Wensheng Yan Wenhua Zhang Junfa Zhu Rui Si Jie Zeng Optimizing reaction paths for methanol synthesis from CO2 hydrogenation via metal-ligand cooperativity
description	Controlling the reaction path is instrumental for developing efficient catalysts for CO2 hydrogenation. Here, the authors report that the ensemble of Pt single atoms coordinated with oxygen atoms in MIL-101 induces distinct reaction path to improve selective hydrogenation of CO2 into methanol relative to nanocrystal counterparts.
format	article
author	Yizhen Chen Hongliang Li Wanghui Zhao Wenbo Zhang Jiawei Li Wei Li Xusheng Zheng Wensheng Yan Wenhua Zhang Junfa Zhu Rui Si Jie Zeng
author_facet	Yizhen Chen Hongliang Li Wanghui Zhao Wenbo Zhang Jiawei Li Wei Li Xusheng Zheng Wensheng Yan Wenhua Zhang Junfa Zhu Rui Si Jie Zeng
author_sort	Yizhen Chen
title	Optimizing reaction paths for methanol synthesis from CO2 hydrogenation via metal-ligand cooperativity
title_short	Optimizing reaction paths for methanol synthesis from CO2 hydrogenation via metal-ligand cooperativity
title_full	Optimizing reaction paths for methanol synthesis from CO2 hydrogenation via metal-ligand cooperativity
title_fullStr	Optimizing reaction paths for methanol synthesis from CO2 hydrogenation via metal-ligand cooperativity
title_full_unstemmed	Optimizing reaction paths for methanol synthesis from CO2 hydrogenation via metal-ligand cooperativity
title_sort	optimizing reaction paths for methanol synthesis from co2 hydrogenation via metal-ligand cooperativity
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/696dbb8bda864e5b9662e05a6e332a6c
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Optimizing reaction paths for methanol synthesis from CO2 hydrogenation via metal-ligand cooperativity

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