Quadruple bonding between iron and boron in the BFe(CO)3 − complex

While main group elements possess four valence orbitals that are accessible for bonding, quadruple bonding to main group elements is very rarely observed. Here the authors report that boron is able to form four bonding interactions with iron in the BFe(CO)3 - anion complex.

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Detalles Bibliográficos
Autores principales: Chaoxian Chi, Jia-Qi Wang, Han-Shi Hu, Yang-Yang Zhang, Wan-Lu Li, Luyan Meng, Mingbiao Luo, Mingfei Zhou, Jun Li
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/697189b1e61349ebbdeff8876bc4d099
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Descripción
Sumario:While main group elements possess four valence orbitals that are accessible for bonding, quadruple bonding to main group elements is very rarely observed. Here the authors report that boron is able to form four bonding interactions with iron in the BFe(CO)3 - anion complex.