Quadruple bonding between iron and boron in the BFe(CO)3 − complex

While main group elements possess four valence orbitals that are accessible for bonding, quadruple bonding to main group elements is very rarely observed. Here the authors report that boron is able to form four bonding interactions with iron in the BFe(CO)3 - anion complex.

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Autores principales:	Chaoxian Chi, Jia-Qi Wang, Han-Shi Hu, Yang-Yang Zhang, Wan-Lu Li, Luyan Meng, Mingbiao Luo, Mingfei Zhou, Jun Li
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/697189b1e61349ebbdeff8876bc4d099
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spelling	oai:doaj.org-article:697189b1e61349ebbdeff8876bc4d0992021-12-02T14:39:18ZQuadruple bonding between iron and boron in the BFe(CO)3 − complex10.1038/s41467-019-12767-52041-1723https://doaj.org/article/697189b1e61349ebbdeff8876bc4d0992019-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12767-5https://doaj.org/toc/2041-1723While main group elements possess four valence orbitals that are accessible for bonding, quadruple bonding to main group elements is very rarely observed. Here the authors report that boron is able to form four bonding interactions with iron in the BFe(CO)3 - anion complex.Chaoxian ChiJia-Qi WangHan-Shi HuYang-Yang ZhangWan-Lu LiLuyan MengMingbiao LuoMingfei ZhouJun LiNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-6 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Chaoxian Chi Jia-Qi Wang Han-Shi Hu Yang-Yang Zhang Wan-Lu Li Luyan Meng Mingbiao Luo Mingfei Zhou Jun Li Quadruple bonding between iron and boron in the BFe(CO)3 − complex
description	While main group elements possess four valence orbitals that are accessible for bonding, quadruple bonding to main group elements is very rarely observed. Here the authors report that boron is able to form four bonding interactions with iron in the BFe(CO)3 - anion complex.
format	article
author	Chaoxian Chi Jia-Qi Wang Han-Shi Hu Yang-Yang Zhang Wan-Lu Li Luyan Meng Mingbiao Luo Mingfei Zhou Jun Li
author_facet	Chaoxian Chi Jia-Qi Wang Han-Shi Hu Yang-Yang Zhang Wan-Lu Li Luyan Meng Mingbiao Luo Mingfei Zhou Jun Li
author_sort	Chaoxian Chi
title	Quadruple bonding between iron and boron in the BFe(CO)3 − complex
title_short	Quadruple bonding between iron and boron in the BFe(CO)3 − complex
title_full	Quadruple bonding between iron and boron in the BFe(CO)3 − complex
title_fullStr	Quadruple bonding between iron and boron in the BFe(CO)3 − complex
title_full_unstemmed	Quadruple bonding between iron and boron in the BFe(CO)3 − complex
title_sort	quadruple bonding between iron and boron in the bfe(co)3 − complex
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/697189b1e61349ebbdeff8876bc4d099
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Quadruple bonding between iron and boron in the BFe(CO)3 − complex

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